Synthesis · Layered coordination polymer with two-dimensional covalent bismuth-organic networks: Semiconductor and lithium ion storage

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: SI

rendered page 2 · Electrode preparations and testing

Metal precursorsBi-DSBDC-DMA framework powder from route_bi_dsbdc_dma_solvothermal

Solventswater slurry; electrolyte for testing was 1 M LiPF6 in EC/DEC (1/1)

Additivescarbon black (Cabot), CMC binder, polypropylene separator (Celgard 2500)

Atmospherenot reported for slurry preparation; dried in vacuum oven

Temperature120

Timeovernight drying

Substrate orientationCu foil current collector

Oxidant / reductantLi metal counter and pseudo-reference electrode in 2032-type coin cells

Work-upBall-milled water slurry pasted on Cu foil.

ActivationVacuum oven drying at 120 C overnight before coin-cell testing.

Scalability contextStandard small coin-cell electrode fabrication; no loading, electrode area or areal mass loading reported.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Bi-DSBDC-DMA MOF solid	6 parts by mass	rendered page 2 · Electrode preparations and testing
Additive	carbon black (Cabot)	3 parts by mass	rendered page 2 · Electrode preparations and testing
Additive	CMC	1 part by mass	rendered page 2 · Electrode preparations and testing
Solvent	water	used to make slurry	rendered page 2 · Electrode preparations and testing
Electrolyte	LiPF6 in EC/DEC (1/1)	1 M	rendered page 2 · Electrode preparations and testing

Complete recipeSource: Both

rendered page 2 · Synthesis of Bi-DSBDC-DMA · Scheme 1 in main text

Metal precursorsBiCl3, 63 mg (0.2 mmol; 315.34 g/mol)

Linker precursorsDMBDC/H2DMBDC, 23 mg (0.1 mmol; 230.26 g/mol)

Solvents8 mL dry DMF

Atmospheresealed glass tube; dry DMF; no inert gas atmosphere reported

Temperature120

Time72

Work-upYellow powder isolated by filtration; washed with DMF, ethanol and THF five times each; dried in air.

ActivationNo activation reported for the as-made framework; vacuum drying at 120 C was studied separately and reduced crystallinity.

Scalability contextSmall sealed-tube solvothermal synthesis; no yield or scale-up study reported.

Show 6 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	BiCl3	63 mg (0.2 mmol)	rendered page 2 · Synthesis of Bi-DSBDC-DMA · Scheme 1 in main text
Linker	DMBDC (also described in the main text as H2DMBDC / 2,5-dimercaptoterephthalic acid)	23 mg (0.1 mmol)	rendered page 2 · Synthesis of Bi-DSBDC-DMA · Scheme 1 in main text
Solvent	dry DMF	8 mL	rendered page 2 · Synthesis of Bi-DSBDC-DMA · Scheme 1 in main text
Solvent	DMF wash	washed 5 times	rendered page 2 · Synthesis of Bi-DSBDC-DMA · Scheme 1 in main text
Solvent	ethanol wash	washed 5 times	rendered page 2 · Synthesis of Bi-DSBDC-DMA · Scheme 1 in main text
Solvent	THF wash	washed 5 times	rendered page 2 · Synthesis of Bi-DSBDC-DMA · Scheme 1 in main text

Partial recipeSource: SI

rendered page 5 · Supplementary figures · Figure S5

Additivesconducting carbon and CMC binder

Atmospherenot reported

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Additive	conducting carbon	3 parts by mass	rendered page 5 · Supplementary figures · Figure S5
Additive	CMC	1 part by mass	rendered page 5 · Supplementary figures · Figure S5