Diffraction Structure — Solid-State Electrochemical Carbon Dioxide Capture by Conductive Metal-Organic Framework Incorporating Nickel Bis(diimine) Units

3 measurement groups · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ni3(HITP)2 recovered after capture-release cycling · Powder

Recovered MOF stripped from CFP, washed with DMSO/ethanol/acetone, dried at 40 C and remeasured.

Context: post-cycling framework stability
Measurement source: S28 · 11. Electrode Materials Before and After Test · Figure S30

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PXRD crystallinity after capture-release cycling	diffraction peaks remained	—	—	Qualitative Qualitative	33097 · Evaluation of the eCC Performance of the MOF Ni3(HITP)2 · Figure S30

Ni(DIB)2 crystals/powder · Powder

Experimental and simulated PXRD pattern for Ni(DIB)2; Rigaku MiniFlex instrument described in SI.

Context: pristine molecular analogue control
Measurement source: S7 · 3. Powder X-ray Diffraction and Solid-State Structures · Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni(DIB)2 PXRD match to simulated pattern	experimental and simulated PXRD pattern shown; synthesis confirmed as consistent with literature	—	—	Qualitative Qualitative	S7 · 3. Powder X-ray Diffraction and Solid-State Structures · Figure S2

As-synthesised Ni3(HITP)2 dark-blue powder · Powder

Rigaku sixth-generation MiniFlex; 600 W, 40 kV, 15 mA; CuKalpha alpha = 1.54 A.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source