Liu Y.-N., Feng L.-J., Bian S.-W. · ACS Applied Electronic Materials · 2022 · 4595-4604
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The CPAMOF electrode and assembled TSC retain capacitance under bending and twisting, supporting flexible textile-supercapacitor use.
Caveat: Flexibility evidence is electrochemical retention under controlled deformation; wearable lifetime under real use is not tested.
4602 · Conclusions · Figures 6 and 8 · Linked to 4 structured results
The assembled symmetrical all-solid-state TSC reaches a high areal energy density of 434 uWh cm-2 at 12.5 mW cm-2.
Caveat: Device metrics are for the reported laboratory textile device; long-term packaged-device endurance beyond deformation tests is not reported.
4601 · Results and Discussion · Figure 7d · Linked to 2 structured results
The article does not report first-hand synthesis or transport/electrochemical characterisation of a freestanding pristine Cu3(HHTP)2 control; all first-hand Cu-MOF data are from the CPAMOF composite electrode.
4596 · 2.2.3 Growth of Conductive MOFs on the CPA · Linked to 2 structured results
The Au nanoparticle layer is the conductive current collector and reduces the textile sheet resistance to 1 Ohm sq-1 before MOF growth.
4598 · Results and Discussion · Figure 2a · Linked to 2 structured results
Low-angle XRD peaks confirm successful growth of a Cu3(HHTP)2 conductive MOF layer on the fibre surface.
Caveat: No standalone pristine Cu3(HHTP)2 control pattern is reported in this article.
4598 · Results and Discussion · Figure 2b · Linked to 1 structured result
The direct contact interface between conductive Cu-MOF and Au layers promotes electron transport and structural stability.
Caveat: The interface role is inferred by the authors from composite structure and electrochemical/EIS trends; no separate interfacial transport experiment is reported.
4598 · Results and Discussion · Figure 3 · Linked to 3 structured results
The b values between 0.5 and 1 indicate a synergistic mechanism combining diffusion-controlled and surface capacitance-controlled charge storage.
4599 · Results and Discussion · Figure 5 · Linked to 4 structured results
The CPAMOF electrode shows pseudocapacitive behaviour attributed to a Cu2+/Cu+ redox transition.
Caveat: Redox attribution is based on CV/GCD behaviour and literature comparison, not direct operando speciation.
4598 · Results and Discussion · Figure 4a,b · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Au-plated polydopamine-modified cotton fabric (CPA) | Au/PDA/cotton compositeAu nanoparticle layer on PDA-modified cotton. · Polydopamine coating; no MOF linker. | unknown · CompositeMetallic Au phase assigned by XRD peaks matching Au (111), (200), (220), (311) and (222). | 4598 · Results and Discussion · Figure 2a |
| Cotton fabric and PDA-modified cotton controls | cotton; PDA/cottonnone · Polydopamine for CP; none for CT. | unknown · UnknownHierarchically porous knitted cotton fibre bundles, modified by PDA nanoparticles in CP. | 4598 · Results and Discussion · Figure 3a-f |
| Cotton/Au/Cu-MOF textile electrode (CPAMOF)Browse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu3(HHTP)2/Au/PDA/cotton compositeCu3(HHTP)2 conductive MOF layer plus Au nanoparticle current collector. · HHTP in Cu3(HHTP)2; polydopamine interlayer on cotton. | unknown · CompositeHierarchically porous textile electrode with a thin Au nanoparticle layer and mulberry-like conductive Cu-MOF nanorod layer on primary cotton fibres. | 4595 · Abstract |
| Conductive Cu-MOF, Cu3(HHTP)2Browse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu3(HHTP)2Cu centres in a conductive copper-catecholate framework. · 2,3,6,7,10,11-Hexahydroxytriphenylene (HHTP). | 2D · CompositeConductive Cu3(HHTP)2 layer assigned by low-angle XRD peaks at 4.8, 9.5, 12.6 and 27.7 degrees, consistent with a previous report. | 4598 · Results and Discussion · Figure 2b |
| Symmetrical all-solid-state textile supercapacitor | CPAMOF/PVA-KCl/filter-paper/CPAMOF deviceCu3(HHTP)2 and Au in the CPAMOF electrodes. · HHTP in Cu3(HHTP)2; PVA gel electrolyte matrix. | unknown · CompositeTwo CPAMOF electrodes assembled with PVA/KCl gel electrolyte and filter-paper separator, sealed by PET film. | 4596 · 2.3 Fabrication of All-Solid-State TSCs |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| CP polydopamine-modified cotton fabricresearch_0214__mat__mat_cotton_controls | Electrode · Pristine Control · Composite | Cotton modified with polydopamine in dopamine solution at pH around 8.5 for 24 h, rinsed and vacuum dried at 50 C.Cotton fabric | 4596 · 2.2.1 Synthesis of Polydopamine-Modified Cotton Fabrics |
| CPA Au-plated cotton/PDA current collectorresearch_0214__mat__mat_au_pda_cotton | Electrode · Pristine Control · Composite | CP immersed in HAuCl4 at pH around 11 for 0.5 h; glucose added as reductant; rinsed and vacuum dried at 50 C.PDA-modified cotton fabric (CP) | 4596 · 2.2.2 Electroless Plating Au Layers on the CP |
| CPAMOF Cu-MOF/Au/cotton electroderesearch_0214__mat__mat_cpamof | Electrode · Target Sample · Composite | CPA immersed in Cu acetate/HHTP H2O/DMF solution after sonication, heated at 90 C for 12 h, stilled overnight, rinsed and vacuum dried at 50 C.Au-plated PDA-modified cotton fabric (CPA) | 4596 · 2.2.3 Growth of Conductive MOFs on the CPA |
| CT cotton fabricresearch_0214__mat__mat_cotton_controls | Electrode · Pristine Control · Unknown | Commercial cotton fabric, cleaned using NaOH solution before modification. | 4596 · 2.1 Materials and 2.2.1 Synthesis |
| Symmetrical all-solid-state TSC assembled from CPAMOF electrodesresearch_0214__mat__mat_tsc_device | Electrode · Composite Sample · Composite | Two CPAMOF electrodes immersed in PVA/KCl gel for 10 min, separated with filter paper under 20 N, gelled at room temperature, sealed by PET film.PET film-sealed textile device | 4596 · 2.3 Fabrication of All-Solid-State TSCs |