cMOF Evidence Base

Synthesis evidence

Surface Structure Construction of Fibers in a Conductive Metal-Organic Framework/Metal/Cotton Electrode for Flexible Textile Supercapacitors

Liu Y.-N., Feng L.-J., Bian S.-W. · ACS Applied Electronic Materials · 2022 · 4595-4604

4 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

4596 · 2.2.1 Synthesis of Polydopamine-Modified Cotton Fabrics

SolventsDI water implied for dopamine and NaOH solutions.
AdditivesNaOH solution used to control pH around 8.5.
Atmosphereair, not explicitly specified
Temperature50 C drying; reaction temperature not stated
Time24
Substrate orientationCotton fabric piece, 4 x 3 cm, immersed in dopamine solution.
Oxidant / reductantDopamine oxidative self-polymerisation; oxidant not specified.
Work-upRinsed thoroughly with DI water and vacuum-dried at 50 C.
Scalability contextUses a 4 x 3 cm cotton fabric piece; no scale-up data.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Othercotton fabric (CT)4 x 3 cm4596 · 2.2.1 Synthesis of Polydopamine-Modified Cotton Fabrics
Additivedopamine hydrochloride (DA)1.0 x 10-3 mol L-14596 · 2.2.1 Synthesis of Polydopamine-Modified Cotton Fabrics
BaseNaOH solution1.0 mol L-14596 · 2.2.1 Synthesis of Polydopamine-Modified Cotton Fabrics
Partial recipeSource: Main

Route 2: Other

4596 · 2.2.2 Electroless Plating Au Layers on the CP

Metal precursorsHAuCl4 solution, 5 x 10-3 mol L-1, 40 mL.
SolventsAqueous solutions implied.
AdditivesNa2CO3 solution used to control pH around 11.
Atmosphereair, not explicitly specified
Temperature50 C drying; plating temperature not stated
Time0.5 h HAuCl4 immersion before glucose addition; subsequent time not stated
Substrate orientationCP fabric immersed in HAuCl4 solution under gentle stirring.
Oxidant / reductantGlucose as reducing reagent, 10 mL of 4.44 x 10-2 mol L-1.
Work-upRinsed with DI water and vacuum-dried at 50 C.
Scalability contextPlating reported using 40 mL HAuCl4 solution and fabric substrate.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherCPNot specified4596 · 2.2.2 Electroless Plating Au Layers on the CP
Metal SourceHAuCl4 solution40 mL · 5 x 10-3 mol L-14596 · 2.2.2 Electroless Plating Au Layers on the CP
BaseNa2CO3 solution1.0 mol L-14596 · 2.2.2 Electroless Plating Au Layers on the CP
Reductantglucose10 mL · 4.44 x 10-2 mol L-14596 · 2.2.2 Electroless Plating Au Layers on the CP
Partial recipeSource: Main

Route 3: Solvothermal

4596 · 2.2.3 Growth of Conductive MOFs on the CPA

Metal precursorsCu(C2H3O2)2.H2O, 0.222 x 10-2 mol.
Linker precursorsHHTP, 0.111 x 10-2 mol.
Solvents3.2 mL H2O/DMF mixture, v/v = 1:1.
Atmosphereair, not explicitly specified
Temperature90
Time12 h heating after 10 min sonication; then stilled overnight at room temperature
Substrate orientationCPA immersed into the reaction solution.
Work-upRinsed with DI water three times and vacuum-dried at 50 C.
Scalability contextSolution volume 3.2 mL for fabric-substrate growth; no scale-up data.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherCPANot specified4596 · 2.2.3 Growth of Conductive MOFs on the CPA
Metal SourceCu(C2H3O2)2.H2O0.222 x 10-2 mol4596 · 2.2.3 Growth of Conductive MOFs on the CPA
LinkerHHTP0.111 x 10-2 mol4596 · 2.2.3 Growth of Conductive MOFs on the CPA
SolventH2O/DMF mixture3.2 mL · v/v = 1:14596 · 2.2.3 Growth of Conductive MOFs on the CPA
Partial recipeSource: Main

Route 4: Other

4596 · 2.3 Fabrication of All-Solid-State TSCs

SolventsPVA/KCl gel solution; composition not stated.
AdditivesKCl electrolyte in PVA gel.
Atmosphereair, not explicitly specified
Temperatureroom temperature gelation
Time0.167 h electrode immersion in gel solution
Substrate orientationTwo identical CPAMOF electrodes with filter paper separator, sealed by PET film.
Work-upGel allowed to become solid at room temperature; device sealed by PET film.
Scalability contextDevice assembled from two CPAMOF textile electrodes.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherCPAMOF electrodestwo electrodes4596 · 2.3 Fabrication of All-Solid-State TSCs
ElectrolytePVA/KCl gel solutionNot specified4596 · 2.3 Fabrication of All-Solid-State TSCs
Otherfilter paper separatorNot specified4596 · 2.3 Fabrication of All-Solid-State TSCs
OtherPET filmNot specified4596 · 2.3 Fabrication of All-Solid-State TSCs