cMOF Evidence Base
Electrical Transport — Size-Dependent Properties of Solution-Processable Conductive MOF Nanocrystals

Measurement evidence

Electrical Transport

Size-Dependent Properties of Solution-Processable Conductive MOF Nanocrystals · Marshall C.R., Dvorak J.P., Twight L.P. et al. · Journal of the American Chemical Society · 2022 · 5784-5794

2 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Co-linear four-point-probe conductivity

Electrical conductivity

Fe(TA)2 thin films doctor-bladed in air · Thin Film

Films made in air and allowed to sit in ambient aerobic conditions for over 1 week; four tungsten carbide probes with 1 mm spacing.

Atmosphere
ambient air
Geometry
co-linear four-point probe
Context
pristine and composite Fe(TA)2 thin films made in air
Measurement source
5792 · Conductivity Measurements · Table S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Conductivity of air-made 130 nm Fe(TA)2 film after over 1 week4.84 x 10-5 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S8
Conductivity of air-made 84 nm Fe(TA)2 film after over 1 weekMarked as a best value within this paper1.53 x 10-4 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S8
Conductivity of air-made 84 nm Fe(TA)2 carbon/PVDF composite film after over 1 weekMarked as a best value within this paper6.30 x 10-4 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S8
Conductivity of air-made bulk Fe(TA)2 film after over 1 week1.08 x 10-5 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S8

Van der Pauw four-point DC conductivity

Electrical conductivity

25 nm Fe(TA)2 doctor-bladed thin film under N2 · Thin Film

Doctor-bladed films made under N2; silver paint contacts at corners; conductivity measured under N2 and after ambient air exposure.

Atmosphere
N2 then ambient air exposure
Geometry
Van der Pauw geometry with copper alligator clips to silver-paint contacts
Context
pristine Fe(TA)2 thin films
Measurement source
5792 · Conductivity Measurements · Figure 7 and Table S9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Conductivity of 25 nm Fe(TA)2 N2-made film after 3 days air exposureMarked as a best value within this paper9.10 x 10-5 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S9
Conductivity of 84 nm Fe(TA)2 N2-made film after 3 days air exposure8.25 x 10-6 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S9
Conductivity of bulk Fe(TA)2 N2-made film after 3 days air exposure1.21 x 10-6 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S9
N2 conductivity of 25 nm Fe(TA)2 filmMarked as a best value within this paper6.11 x 10-7 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S9
N2 conductivity of 84 nm Fe(TA)2 film5.06 x 10-8 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S9
N2 conductivity of bulk Fe(TA)2 film6.33 x 10-9 S/cm——SI Table
Exact Reported		27 · S4 Additional Electrochemical Data · Table S9