Microscopy Morphology — Size-Dependent Properties of Solution-Processable Conductive MOF Nanocrystals

4 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CoTA2 bulk and nanosized series with 1-methylimidazole · Powder

Preliminary CoTA2 bulk and nanoparticle syntheses with varying 1-methylimidazole equivalents.

Context: pristine CoTA2 powder/nanoparticles
Measurement source: 10 · S2 Discussion of Fe(TA)2 nanoparticle syntheses · Figure S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CoTA2 SEM particle size at 0.05 equiv 1-mIm	42 +/- 7 nm	—	+/- 7 nm	Figure Axis Rounded Reported	10 · S2 Discussion of Fe(TA)2 nanoparticle syntheses · Figure S7
CoTA2 SEM particle size at 0.3 equiv 1-mImMarked as a best value within this paper	17 +/- 7 nm	—	+/- 7 nm	Figure Axis Rounded Reported	10 · S2 Discussion of Fe(TA)2 nanoparticle syntheses · Figure S7
CoTA2 bulk SEM particle size	92 +/- 11 nm	—	+/- 11 nm	Figure Axis Rounded Reported	10 · S2 Discussion of Fe(TA)2 nanoparticle syntheses · Figure S7

Fe(TA)2 nanoparticles made with alternate modulators · Powder

Exploratory Fe(TA)2 syntheses with 5-bromo-1-methylimidazole, 1-benzyl-2-methylimidazole and n-butylamine.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
SEM particle size with 0.218 equiv 1-benzyl-2-methylimidazole	22 +/- 3 nm	—	+/- 3 nm	SI Table Exact Reported	13 · S2 Basic characterization · Table S4
SEM particle size with 0.218 equiv 5-bromo-1-methylimidazole	78 +/- 6 nm	—	+/- 6 nm	SI Table Exact Reported	13 · S2 Basic characterization · Table S3
SEM particle size with 0.218 equiv n-butylamine	21 +/- 2 nm	—	+/- 2 nm	Caption Exact Reported	7 · S2 Synthesis of Fe(TA)2 under different conditions · Figure S3

Fe(TA)2 nanoparticles, 25 nm SEM size · Powder

DMF suspensions filtered and measured in a custom air-free 1 mm quartz cuvette; six measurements one minute apart.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Solvated radius of 25 nm Fe(TA)2 nanoparticles in DMF	30 +/- 5 nm	—	+/- 5 nm	Caption Exact Reported	16 · S2 Basic characterization · Figure S13

Fe(TA)2 nanoparticle series synthesised with 1-methylimidazole · Powder

SEM samples drop-cast from DMF onto silicon and dried under N2; >200 particles measured when SEM-resolved. Scherrer analysis from PXRD for all sizes.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
SEM particle size, 0.055 equiv 1-mIm	130 +/- 10 nm	—	+/- 10 nm	SI Table Exact Reported	12 · S2 Basic characterization · Table S2
SEM particle size, 0.109 equiv 1-mIm	84 +/- 20 nm	—	+/- 20 nm	SI Table Exact Reported	12 · S2 Basic characterization · Table S2
SEM particle size, 0.218 equiv 1-mIm	48 +/- 3 nm	—	+/- 3 nm	SI Table Exact Reported	12 · S2 Basic characterization · Table S2
SEM particle size, 0.436 equiv 1-mIm	25 +/- 3 nm	—	+/- 3 nm	SI Table Exact Reported	12 · S2 Basic characterization · Table S2
SEM particle size, 0.709 equiv 1-mIm	16 +/- 2 nm	—	+/- 2 nm	SI Table Exact Reported	12 · S2 Basic characterization · Table S2
Scherrer particle size, 10.9 equiv 1-mImMarked as a best value within this paper	5.5 nm	—	—	SI Table Exact Reported	12 · S2 Basic characterization · Figure S9 and Table S2
Scherrer particle size, 3.00 equiv 1-mIm	6.8 nm	—	—	SI Table Exact Reported	12 · S2 Basic characterization · Figure S9 and Table S2