Diffraction Structure — Humidity-mediated anisotropic proton conductivity through the 1d channels of co-mof-74

Measurement evidence

Diffraction Structure

Humidity-mediated anisotropic proton conductivity through the 1d channels of co-mof-74 · Javed A., Strauss I., Bunzen H. et al. · Nanomaterials · 2020 · 1-9

3 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Experimental and simulated powder XRD comparison

Co-MOF-74 powder sample · Powder

Supplementary powder XRD pattern compared with literature/simulated Co-MOF-74 pattern.

Context
pristine_framework
Measurement source
1 · Supplementary Material · Figure S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
experimental/simulated powder XRD matchExperimental and simulated Co-MOF-74 powder XRD pattern shownCaption
Qualitative
1 · Supplementary Material · Figure S2

Structure description from cited Co-MOF-74 crystallographic data and VESTA rendering

large Co-MOF-74 single crystals · Single Crystal

Solvent-free Co-MOF-74 structure viewed along crystallographic c axis; ambient humid air expected to coordinate water to open Co sites.

Context
pristine_framework
Measurement source
1-2 · Introduction · Figure 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
linear micropore diameter1.1 nmText
Rounded Reported
1 · Introduction
trigonal space group numberspace group 148, R-3Text
Exact Reported
1 · Introduction

Temperature-resolved powder XRD, Panalytical Empyrean

Co-MOF-74 powder sample · Powder

93% relative humidity; CHC plus+ chamber; Cu radiation; 20-60 C in 5 C steps after 15 min isothermal steps; 5-50 degrees 2theta.

Atmosphere
93% relative humidity
Context
pristine_framework
Measurement source
2-4 · Materials and Methods; Results and Discussion · Figure 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
110 reflection position110 at 6.5 degreesCaption
Rounded Reported
4 · Figure caption · Figure 3
300 reflection position300 at 11.6 degreesCaption
Rounded Reported
4 · Figure caption · Figure 3
first diffraction peak with minor intensity changesfirst diffraction peak at 6.7 degreesText
Rounded Reported
3 · Results and Discussion · Figure 3
XRD stability relative humidity93% relative humidityText
Exact Reported
3 · Results and Discussion · Figure 3
hydrothermal XRD stability windowstable from 20-60 C at 93% relative humidityText
Range
3-4 · Results and Discussion · Figure 3