Partial recipeSource: Main
Route 1: Solvothermal
2 · Materials and Methods
Metal precursors750 mg cobalt nitrate hexahydrate, Co(NO3)2.6H2O, 99%, Sigma-Aldrich
Linker precursors144 mg 2,5-dihydroxy-terephthalic acid (DHBDC), 98%, Sigma-Aldrich
Solvents60 mL mixture of EtOH, DMF and H2O in a 1:1:1 ratio; MeOH used for washing/solvent exchange
AtmosphereSolvothermal atmosphere not specified; drying/activation under reduced pressure/vacuum
Temperature131
Time24
Work-upAfter cooling to room temperature, crystals were washed and solvent-exchanged with MeOH.
ActivationCrystals were dried under reduced pressure and activated under vacuum at 160 C overnight.
Scalability contextLarge crystals of a few hundred micrometres were obtained; no scale-up discussion is provided.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | cobalt nitrate hexahydrate (Co(NO3)2.6H2O, 99% Sigma-Aldrich, Taufkirchen, Germany) | 750 mg | 2 · Materials and Methods |
| Linker | 2,5-dihydroxy-terephthalic acid (DHBDC, 98% Sigma-Aldrich, Taufkirchen, Germany) | 144 mg | 2 · Materials and Methods |
| Solvent | EtOH | part of 60 mL 1:1:1 EtOH/DMF/H2O mixture | 2 · Materials and Methods |
| Solvent | DMF | part of 60 mL 1:1:1 EtOH/DMF/H2O mixture | 2 · Materials and Methods |
| Solvent | H2O | part of 60 mL 1:1:1 EtOH/DMF/H2O mixture | 2 · Materials and Methods |
| Solvent | MeOH | used for washing/solvent exchange | 2 · Materials and Methods |