Electrical Transport — Improved electrical conductivity of Co(ii) and Cu(ii) ladder polymers in the fabrication of photoresponsive Schottky devices

Measurement evidence

Electrical Transport

Improved electrical conductivity of Co(ii) and Cu(ii) ladder polymers in the fabrication of photoresponsive Schottky devices · Dutta B., Das D., Raksha K. et al. · Materials Advances · 2022 · 215-222

6 measurement groups · 30 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Current-voltage (I-V) measurement

Al/Co-CP/ITO Schottky device · Thin Film

Applied bias +/-1 V under dark and light conditions; conductivity and photosensitivity listed in Table 1.

Temperature
not reported
Atmosphere
dark and light irradiation; light source intensity not reported
Geometry
Al/Co-CP/ITO metal-semiconductor Schottky device; effective diode area 7.065 x 10^-6 m^-2
Context
pristine CP thin-film device
Measurement source
220 · Current-voltage (I-V) measurement · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
photosensitivity S0.41Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 1
dc conductivity dark4.78 x 10^-6 S m^-14.78e-8 S cm^-1Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 1
dc conductivity light6.15 x 10^-6 S m^-16.15e-8 S cm^-1Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 1

Thermionic-emission/Cheung analysis of I-V curves

Al/Co-CP/ITO Schottky device · Thin Film

G(J) vs J and H(J) vs J fits under dark and light conditions.

Temperature
not reported
Atmosphere
dark and light irradiation
Geometry
Al/Co-CP/ITO Schottky device
Context
pristine CP thin-film device
Measurement source
220 · Current-voltage (I-V) measurement · Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
barrier height dark0.72 eVTable
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
barrier height light0.71 eVTable
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
ideality factor dark0.89Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
ideality factor light1.15Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
series resistance dark23.42 kOhmTable
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
series resistance light16.41 kOhmTable
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2

Space-charge-limited current (SCLC), capacitance-frequency and transient photocurrent analysis

Al/Co-CP/ITO Schottky device · Thin Film

Log I-V slopes identify ohmic, SCLC and high-injection regions; mobility and transit time calculated using Mott-Gurney-type equations.

Temperature
not reported
Atmosphere
dark and light irradiation
Geometry
Al/Co-CP/ITO Schottky device
Context
pristine CP thin-film device
Measurement source
221 · SCLC parameters · Table 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
epsilon r1.15 x 10^-10Table
Exact Reported
221 · SCLC parameters · Table 3
mobility dark6.94 x 10^-7 m^2 V^-1 s^-1Table
Exact Reported
221 · SCLC parameters · Table 3
mobility light8.72 x 10^-7 m^2 V^-1 s^-1Table
Exact Reported
221 · SCLC parameters · Table 3
I-V log-log regionsregion-I: I proportional to V; region-II: I proportional to V^2; region-III: I proportional to V^n, n > 2Text
Qualitative
220 · SCLC discussion · Fig. 7b
transit time dark1.66 x 10^-6 sTable
Exact Reported
221 · SCLC parameters · Table 3
transit time light1.31 x 10^-6 sTable
Exact Reported
221 · SCLC parameters · Table 3

Current-voltage (I-V) measurement

Al/Cu-CP/ITO Schottky device · Thin Film

Applied bias +/-1 V under dark and light conditions; conductivity and photosensitivity listed in Table 1.

Temperature
not reported
Atmosphere
dark and light irradiation; light source intensity not reported
Geometry
Al/Cu-CP/ITO metal-semiconductor Schottky device; effective diode area 7.065 x 10^-6 m^-2
Context
pristine CP thin-film device
Measurement source
220 · Current-voltage (I-V) measurement · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
photosensitivity SMarked as a best value within this paper0.86Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 1
dc conductivity darkMarked as a best value within this paper19.97 x 10^-6 S m^-11.997e-7 S cm^-1Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 1
dc conductivity lightMarked as a best value within this paper70.61 x 10^-6 S m^-17.061e-7 S cm^-1Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 1

Thermionic-emission/Cheung analysis of I-V curves

Al/Cu-CP/ITO Schottky device · Thin Film

G(J) vs J and H(J) vs J fits under dark and light conditions.

Temperature
not reported
Atmosphere
dark and light irradiation
Geometry
Al/Cu-CP/ITO Schottky device
Context
pristine CP thin-film device
Measurement source
220 · Current-voltage (I-V) measurement · Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
barrier height dark0.70 eVTable
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
barrier height light0.66 eVTable
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
ideality factor dark1.43Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
ideality factor light1.01Table
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
series resistance dark4.21 kOhmTable
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2
series resistance light2.60 kOhmTable
Exact Reported
220 · Current-voltage (I-V) measurement · Table 2

Space-charge-limited current (SCLC), capacitance-frequency and transient photocurrent analysis

Al/Cu-CP/ITO Schottky device · Thin Film

Log I-V slopes identify ohmic, SCLC and high-injection regions; mobility and transit time calculated using Mott-Gurney-type equations.

Temperature
not reported
Atmosphere
dark and light irradiation
Geometry
Al/Cu-CP/ITO Schottky device
Context
pristine CP thin-film device
Measurement source
221 · SCLC parameters · Table 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
epsilon r2.34 x 10^-10Table
Exact Reported
221 · SCLC parameters · Table 3
mobility dark1.94 x 10^-6 m^2 V^-1 s^-1Table
Exact Reported
221 · SCLC parameters · Table 3
mobility lightMarked as a best value within this paper3.70 x 10^-6 m^2 V^-1 s^-1Table
Exact Reported
221 · SCLC parameters · Table 3
I-V log-log regionsregion-I: I proportional to V; region-II: I proportional to V^2; region-III: I proportional to V^n, n > 2Text
Qualitative
220 · SCLC discussion · Fig. 7b
transit time dark5.51 x 10^-7 sTable
Exact Reported
221 · SCLC parameters · Table 3
transit time lightMarked as a best value within this paper2.90 x 10^-7 sTable
Exact Reported
221 · SCLC parameters · Table 3