Complete recipeSource: Main
Route 1: Solvothermal
2 · 2.2. Fabrication of self-standing Ni-Fe(PDC)@graphite rod electrode
Metal precursors25 mmol Ni(NO3)2,6H2O; 15 mmol Fe(NO3)3,9H2O
Linker precursors0.350 g 2,6-pyridinedicarboxylic acid (PDC)
Solvents50 ml DMF for metal salts; 30 ml DMF for PDC
Atmospherenot specified
Temperature150
Time24
Substrate orientationgraphite rod present in 100 ml autoclave; orientation not specified
Work-upAutoclave slowly cooled to room temperature; MOF-deposited graphite rod carefully washed and dried at 80 deg C overnight.
ActivationDried at 80 deg C overnight; BET samples degassed at 120 deg C for 12 h before porosity measurement.
Scalability contextOne-step solvothermal rod coating in a 100 ml autoclave; authors describe it as simple, cost-effective and waste-reducing.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Ni(NO3)2,6H2O | 25 mmol | 2 · 2.2. Fabrication of self-standing Ni-Fe(PDC)@graphite rod electrode |
| Metal Source | Fe(NO3)3,9H2O | 15 mmol | 2 · 2.2. Fabrication of self-standing Ni-Fe(PDC)@graphite rod electrode |
| Linker | 2,6-pyridinedicarboxylic acid (PDC) | 0.350 g | 2 · 2.2. Fabrication of self-standing Ni-Fe(PDC)@graphite rod electrode |
| Solvent | DMF | 50 ml + 30 ml | 2 · 2.2. Fabrication of self-standing Ni-Fe(PDC)@graphite rod electrode |
| Other | graphite rod | length 100 mm; diameter 3 mm | 2 · 2.2. Fabrication of self-standing Ni-Fe(PDC)@graphite rod electrode |