Synthesis · A chiral SrSi2 (srs) superstructure constructed by a dual interaction system showing isotropic electrical conductivity

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Both

Route 1: Other

main p.3 · Main text · Figs. S3, S5

Metal precursorscompound 1

Solventsmixed MeOH/acetone

Atmospherenot specified

Temperaturenot specified

Timenot specified

Work-upCrystals recovered from solution of compound 1 in mixed MeOH/acetone by recrystallisation.

Activationnot specified

Scalability contextRegeneration described qualitatively; no cycle number, recovery yield, or scale reported in the available text.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	compound 1	Not specified	main p.3 · Main text · Figs. S3, S5
Solvent	MeOH	mixed MeOH/acetone	main p.3 · Main text · Figs. S3, S5
Solvent	acetone	mixed MeOH/acetone	main p.3 · Main text · Figs. S3, S5

Complete recipeSource: Both

Route 2: Other

SI office text · Experimental Section

Metal precursorsAgOTf (silver triflate), 150 mg, 0.58 mmol

Linker precursorsL = tris(2-naphthimidazolylmethyl)amine, 28 mg, 0.05 mmol

SolventsMeOH/DMF/acetone, 6 mL total, v/v/v 8/1/3; equivalent to main-text MeOH/acetone/DMF 8/3/1

Additivestetrabutylammonium bromide, 10 mg, 0.03 mmol

Atmospherenot specified

Temperatureroom temperature

Time2 h stirring plus 3 days undisturbed crystallisation

Work-upTurbid solution stirred at room temperature for 2 h; insoluble matter removed by filtration; filtrate left undisturbed at room temperature for 3 days; crystals obtained.

ActivationNo activation reported; main text states the 3D pi-stacked supramolecular structure collapses upon solvent removal.

Scalability contextCrystallisation recipe at milligram ligand scale; yield 65% based on L; no scale-up demonstrated.

Show 6 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	L (tris(2-naphthimidazolylmethyl)amine)	28 mg, 0.05 mmol	SI office text · Experimental Section
Metal Source	AgOTf	150 mg, 0.58 mmol	SI office text · Experimental Section
Additive	tetrabutylammonium bromide	10 mg, 0.03 mmol	SI office text · Experimental Section
Solvent	MeOH	part of 6 mL MeOH/DMF/acetone mixture, v/v/v 8/1/3	SI office text · Experimental Section
Solvent	DMF	part of 6 mL MeOH/DMF/acetone mixture, v/v/v 8/1/3	SI office text · Experimental Section
Solvent	acetone	part of 6 mL MeOH/DMF/acetone mixture, v/v/v 8/1/3	SI office text · Experimental Section

Partial recipeSource: Both

Route 3: Drop Cast

SI office text · Regeneration of 1 and fabrication of thin film of 1 · Fig. S6

Metal precursorscompound 1

Solventsnot specified

Atmospherenot specified

Temperaturenot specified

Timenot specified

Substrate orientationsubstrate not specified

Work-upThin film prepared by simple cast coating/drop casting.

Activationnot specified

Scalability contextThin-film processability claimed qualitatively; no film area, thickness, substrate, or electrical measurement reported.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	compound 1	Not specified	SI office text · Regeneration of 1 and fabrication of thin film of 1 · Fig. S6