Dong Y.-L., Jing Z.-Y., Wu Q.-J. et al. · Journal of Materials Chemistry A · 2023 · 8739-8746
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Optimal Vg-Por(Co)-MOF(9:1) reaches high CO2-to-CO performance in MEA, with FECO near 94%, jCO 111.1 mA cm-2 and TOF about 4.6 x 10^3 h-1.
Caveat: MEA voltage is reported as full-cell voltage rather than RHE potential.
p006 / article 8744 · Results and discussion · Fig. 5 · Linked to 3 structured results
Viologen incorporated in the MOF backbone transfers electrons more effectively than methyl-viologen located in channels or on surfaces.
Caveat: The main text calls MV@Por a physical mixture, while SI gives a solvothermal recipe; exact guest location is inferred from authors' comparison.
p005 / article 8743 · Results and discussion · Fig. S32-S34 · Linked to 2 structured results
The Por(Co)-MOF, Vg-MOF and Vg-Por(Co)-MOF series share the same UiO-type topology and retain Co-N4 porphyrin coordination without Co or CoO particles.
Caveat: Exact empirical framework formulae are not reported in the extracted text.
p003-p004 / article 8741-8742 · Results and discussion · Fig. 3 · Linked to 3 structured results
Backbone-integrated viologen ETM improves electron-transfer capacity and raises Vg-Por(Co)-MOF(9:1) conductivity about eightfold over Por(Co)-MOF.
Caveat: Conductivity is low and was measured by two-contact pressed-pellet method, so contact resistance may contribute.
p004 / article 8742 · Results and discussion · Fig. S24 · Linked to 2 structured results
Higher Cdl and smaller EIS semicircle for Vg-Por(Co)-MOF(9:1) indicate faster interfacial charge transfer and larger electrochemically active surface area.
Caveat: EIS comparison is qualitative from Nyquist plots; Cdl is an indirect ECSA proxy.
p004-p005 / article 8742-8743 · Results and discussion · Fig. S25-S30 · Linked to 2 structured results
Reversible Vg redox states accelerate proton-coupled electron transfer, promoting formation of *COOH at Co-N4 sites and subsequent CO generation.
Caveat: Mechanistic assignment is inferred from in situ UV/ATR-IR bands rather than direct kinetic isotope or operando structural proof.
p006 / article 8744 · Results and discussion · Fig. S40-S43 · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| MV@Por(Co)-MOF(9:1) | Methyl-viologen-loaded Por(Co)-MOF control; exact formula not reportedHf6-based Por(Co)-MOF framework · Por(Co) linker plus methyl viologen additive/guest | 3D · CompositeNon-backbone-integrated viologen control used to compare with covalently integrated Vg-Por(Co)-MOF(9:1). | p005 / article 8743 · Results and discussion · Fig. S32-S34 |
| Por(Co)-MOF | Hf6(mu3-O)4(mu3-OH)4 Por(Co)-linked UiO-type MOF; exact formula not reported12-connected Hf6(mu3-O)4(mu3-OH)4 secondary building units · 5,15-di(p-benzoato)-10,20-diphenyl-porphyrin cobalt(II), Por(Co) | 3D · PristineUiO-type open framework with 1.6 nm triangular channels and 2.8/2.0 nm octahedral/tetrahedral voids. | p002 / article 8740 · Results and discussion · Fig. S8 |
| Vg-MOF | Zr-based UiO-type viologen MOF; exact formula not reportedZr oxo cluster from ZrOCl2.8H2O route; Vg-MOF EDS maps Zr · [H2bpybdc]Cl2 viologen dicarboxylate linker (Vg) | 3D · PristineSame PXRD topology as the Por(Co)-MOF/Vg-Por(Co)-MOF family; Vg-MOF route uses Zr source in SI. | p002 / article 8740 · Results and discussion · Fig. S7, Fig. S23 |
| Vg-Por(Co)-MOF(n:1) | Multivariate Hf6(mu3-O)4(mu3-OH)4 MOF with Por(Co) and Vg linkers; exact formula not reported12-connected Hf6(mu3-O)4(mu3-OH)4 secondary building units · Mixed Por(Co) and Vg dicarboxylate linkers with Por(Co):Vg ratios n:1 | 3D · PristineMultivariate UiO-type MOF in which Vg electron-transfer mediator modules are inserted into cobalt-porphyrin MOF backbones. | p002 / article 8740 · Results and discussion · Fig. 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| MOF sample seriesresearch_0250__mat__mat_vg_por_co_mof | Powder · Paper Level Unspecified · Unknown | as-synthesised | p002 / article 8740 · Results and discussion · Fig. S7 |
| MV@Por(Co)-MOF(9:1)research_0250__mat__mat_mv_por_co_mof | Powder · Composite Sample · Guest Loaded | solvothermal guest/additive control; washed, solvent-exchanged in DMF, acetone washed and dried | p013 · Section S3 · Synthesis of MV@Por(Co)-MOF(9:1) |
| Por(Co)-MOFresearch_0250__mat__mat_por_co_mof | Powder · Pristine Control · Pristine Framework | washed, solvent-exchanged in DMF, acetone washed and dried | p012 · Section S3 · Synthesis of Por(Co)-MOF |
| Vg-MOFresearch_0250__mat__mat_vg_mof | Powder · Pristine Control · Pristine Framework | washed, solvent-exchanged in DMF, acetone washed and dried | p011 · Section S3 · Synthesis of Vg-MOF |
| Vg-Por(Co)-MOF(1:1)research_0250__mat__mat_vg_por_co_mof | Powder · Target Sample · Pristine Framework | washed, solvent-exchanged in DMF, acetone washed and dried | p013 · Section S3 · Synthesis of Vg-Por(Co)-MOF(1:1) |
| Vg-Por(Co)-MOF(2:1)research_0250__mat__mat_vg_por_co_mof | Powder · Target Sample · Pristine Framework | washed, solvent-exchanged in DMF, acetone washed and dried | p013 · Section S3 · Synthesis of Vg-Por(Co)-MOF(2:1) |
| Vg-Por(Co)-MOF(5:1)research_0250__mat__mat_vg_por_co_mof | Powder · Target Sample · Pristine Framework | washed, solvent-exchanged in DMF, acetone washed and dried | p012 · Section S3 · Synthesis of Vg-Por(Co)-MOF(5:1) |
| Vg-Por(Co)-MOF(9:1)research_0250__mat__mat_vg_por_co_mof | Powder · Target Sample · Pristine Framework | washed, solvent-exchanged in DMF, acetone washed and dried; also pressed as pellet and made into electrodesAFM height profile about 2.5 nm in Fig. 2c; family nanosheets 1-4 nm after ultrasonic treatment | p001 / article 8739 · Abstract |