Microscopy Morphology — Morphological control of a metal-organic framework for single-crystal electronic device fabrication

10 measurement groups · 29 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

optical microscopy and crystal-size statistics

Zn-1 reproduced literature Zn2(TTFTB) crystals · Single Crystal

25 single crystals randomly selected from each sample for length/width statistics

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) crystals
Measurement source: 22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-1 average length	21.55 +/- 8.08 um	—	+/- 8.08 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-1 average cross-sectional width	10.22 +/- 2.94 um	—	+/- 2.94 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-1 length-to-width ratio	2.13	—	—	SI Table Exact Reported	22 · Table S1 · Table S1

optical microscopy and length distribution

Zn-10 sequential ligand/Zn2+ addition crystals · Single Crystal

25 Zn-10 crystals measured for length distribution

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) mechanistic trial
Measurement source: 4 · Results and discussions · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-10 average length	334 um	—	—	Text Rounded Reported	4 · Results and discussions · Figure S13

optical microscopy and crystal-size statistics

Zn-2 water-content trial crystals · Single Crystal

25 single crystals randomly selected from each sample for length/width statistics

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) crystals
Measurement source: 22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-2 average length	84.38 +/- 16.11 um	—	+/- 16.11 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-2 average cross-sectional width	4.82 +/- 1.57 um	—	+/- 1.57 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-2 length-to-width ratio	19.25	—	—	SI Table Exact Reported	22 · Table S1 · Table S1

optical microscopy and crystal-size statistics

Zn-3 fast heating/cooling-rate crystals · Single Crystal

25 single crystals randomly selected from each sample for length/width statistics

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) crystals
Measurement source: 22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-3 average length	32.18 +/- 11.17 um	—	+/- 11.17 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-3 average cross-sectional width	2.25 +/- 0.88 um	—	+/- 0.88 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-3 length-to-width ratio	14.94	—	—	SI Table Exact Reported	22 · Table S1 · Table S1

optical microscopy and crystal-size statistics

Zn-4 short reaction-time crystals · Single Crystal

25 single crystals randomly selected from each sample for length/width statistics

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) crystals
Measurement source: 22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-4 average length	20.86 +/- 4.07 um	—	+/- 4.07 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-4 average cross-sectional width	7.04 +/- 2.28 um	—	+/- 2.28 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-4 length-to-width ratio	3.21	—	—	SI Table Exact Reported	22 · Table S1 · Table S1

optical microscopy and crystal-size statistics

Zn-5 high-temperature crystals · Single Crystal

25 single crystals randomly selected from each sample for length/width statistics

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) crystals
Measurement source: 22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-5 average length	63.48 +/- 12.14 um	—	+/- 12.14 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-5 average cross-sectional width	22.01 +/- 2.93 um	—	+/- 2.93 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-5 length-to-width ratio	3.12	—	—	SI Table Exact Reported	22 · Table S1 · Table S1

optical microscopy and crystal-size statistics

Zn-6 organic-solvent trial crystals · Single Crystal

25 single crystals randomly selected from each sample for length/width statistics

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) crystals
Measurement source: 22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-6 average length	46.23 +/- 15.31 um	—	+/- 15.31 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-6 average cross-sectional width	5.17 +/- 1.59 um	—	+/- 1.59 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-6 length-to-width ratio	2.91	—	—	SI Table Exact Reported	22 · Table S1 · Table S1

optical microscopy and crystal-size statistics

Zn-7 pH/acetic-acid trial crystals · Single Crystal

25 single crystals randomly selected from each sample for length/width statistics

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) crystals
Measurement source: 22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-7 average length	104.90 +/- 31.98 um	—	+/- 31.98 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-7 average cross-sectional width	37.54 +/- 9.00 um	—	+/- 9.00 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-7 length-to-width ratio	9.14	—	—	SI Table Exact Reported	22 · Table S1 · Table S1

optical microscopy and crystal-size statistics

Zn-8 high-Zn2+ concentration crystals · Single Crystal

25 single crystals randomly selected from each sample for length/width statistics

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) crystals
Measurement source: 22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-8 average length	13.52 +/- 5.81 um	—	+/- 5.81 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-8 average cross-sectional width	3.84 +/- 1.06 um	—	+/- 1.06 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-8 length-to-width ratio	2.80	—	—	SI Table Exact Reported	22 · Table S1 · Table S1

optical microscopy and crystal-size statistics

Zn-9 large Zn2(TTFTB) crystals · Single Crystal

25 single crystals randomly selected from each sample for length/width statistics

Atmosphere: ambient air
Geometry: single-crystal optical dimensions
Context: pristine Zn2(TTFTB) crystals
Measurement source: 22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-9 average lengthMarked as a best value within this paper	450.25 +/- 134.21 um	—	+/- 134.21 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-9 average cross-sectional width	143.37 +/- 35.97 um	—	+/- 35.97 um	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-9 length-to-width ratio	3.47	—	—	SI Table Exact Reported	22 · Table S1 · Table S1
Zn-9 longest observed crystal lengthMarked as a best value within this paper	exceeding 800 um	—	—	Text Approximate	4 · Attempts to grow long crystals for manual fabrication · Fig. 5d