Measurement evidence
A europium(III) based metal-organic framework: Bifunctional properties related to sensing and electronic conductivity · Hao Z., Yang G., Song X. et al. · Journal of Materials Chemistry A · 2014 · 237-244
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
I2-incorporated EuL crystals · Single Crystal
Representative outgassed, I2-incorporated, Cu2+-incorporated, acetone-incorporated and DMF-incorporated EuL samples compared with simulated pattern.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| I2-incorporated EuL PXRD framework retention | remains highly crystallized and retains the main framework features of EuL | — | — | Qualitative Qualitative | 8 · Figure S6 caption · Fig. S6 |
As-synthesised EuL colourless crystals · Single Crystal
Bruker Apex CCD, graphite-monochromated Mo-Kalpha radiation; main text says 273 K, CIF lists 293(2) K.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Unit-cell volume | 4784(3) A^3 | — | (3) | Text Exact Reported | CIF text · cell parameters · _cell_volume |
| Channel A approximate size | 9.5 x 8.4 A | — | — | Text Rounded Reported | 238 · Structure for EuL · Fig. 1 |
| Channel B approximate size | 7.8 x 9.2 A | — | — | Text Rounded Reported | 238 · Structure for EuL · Fig. 1 |
| O-Eu-O bond angle range | 48.76(8)-153.96(12) deg | — | (8)-(12) | Text Range | 238 · Structure for EuL · Table S1 |
| Eu-O bond length range | 2.293(3) to 2.503(3) A | — | (3) | Text Range | 238 · Structure for EuL · Table S1 |
| CIF formula sum | C66 H34 Eu4 N2 O34 | — | — | Text Exact Reported | CIF text · data_hao · _chemical_formula_sum |
| Solvent-accessible volume | 1717.9 A^3, corresponding to 35.9% (4784 A^3) of desolvated EuL | 35.9 % | — | Text Exact Reported | 239 · Structure for EuL |
| Space group | P-1 | — | — | Text Exact Reported | CIF text · data_hao · _symmetry_space_group_name_H-M |