Hu M., Liu J., Song S. et al. · ACS Catalysis · 2022 · 3238-3248
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
NiZrCu-BDC outperforms Ni-BDC and NiZr-BDC for liquid-product photocatalytic CO2 reduction.
Caveat: Application performance rather than intrinsic electrical transport.
p006 · Results and Discussion · Figure 5 · Linked to 6 structured results
NiZrCu-BDC retains morphology and crystal structure after five photocatalytic cycles.
Caveat: Based on post-reaction XRD, XPS, TEM and EDS figures; no long-term ageing data.
p007 · Results and Discussion · Figures S20-S22 · Linked to 1 structured result
The ultra-thin NiZrCu-BDC nanosheet shortens the electron transport path and supports higher photocatalytic activity.
Caveat: No direct DC conductivity measurement was reported.
p007 · Conclusions · Linked to 3 structured results
Zr and Cu doping enriches electron density at Ni sites, promoting CO2 chemisorption and COOH*/CHO formation.
Caveat: Supported by spectroscopy trends and DFT models.
p001 · Abstract · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| NiZrCu-BDC computational model | Zr/Cu-substituted Ni-BDCNi, Zr and Cu · terephthalic acid / BDC | 3D · Model SystemZr/Cu-substituted Ni-BDC model with Ni, Zr and Cu reaction-site variants | p009 · Computational Details · Figure S23 |
| NiZr-BDC computational model | Zr-substituted Ni-BDCNi and Zr · terephthalic acid / BDC | 3D · Model SystemZr-substituted Ni-BDC model with Ni and Zr reaction-site variants | p009 · Computational Details · Figure S23 |
| Ni-BDC computational model | Ni18O55C73H18Ni · terephthalic acid / BDC | 3D · Model Systemrhombohedral primitive Ni-BDC cell containing two tetrahedral cages | p009 · Computational Details · Figure S23 |
| NiZrCu-BDC | NiZrCu-BDCNi, Zr and Cu · terephthalic acid / BDC | 2D · Pristinetarget trimetallic ultra-thin two-dimensional MOF nanosheet | p001 · Abstract |
| NiZr-BDC | NiZr-BDCNi and Zr · terephthalic acid / BDC | 2D · Pristinebimetallic ultra-thin two-dimensional MOF nanosheet retaining the Ni-BDC framework | p002 · Results and Discussion · Figure 1/Figure 2 |
| Ni-BDC | Ni-BDCNi · terephthalic acid / BDC | 2D · Pristineultra-thin two-dimensional MOF nanosheet; XRD matches simulated Ni-BDC and (200) peak | p002 · Results and Discussion · Figure 1/Figure 2 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| NiZrCu-BDC(Ni) modelresearch_0292__mat__mat_DFT_NiZrCu_BDC_model | Model · Model System · Model | periodic DFT model | p014 · Supporting Information · Figure S23 |
| NiZr-BDC(Ni) modelresearch_0292__mat__mat_DFT_NiZr_BDC_model | Model · Model System · Model | periodic DFT model | p014 · Supporting Information · Figure S23 |
| Ni-BDC modelresearch_0292__mat__mat_DFT_Ni_BDC_model | Model · Model System · Model | periodic DFT model | p014 · Supporting Information · Figure S23 |
| NiZrCu-BDC catalyst electroderesearch_0292__mat__mat_NiZrCu_BDC | Electrode · Target Sample · Composite | target_sampleglassy carbon or FTO | p008 · Photoelectrochemical Performance |
| NiZrCu-BDC nanosheetsresearch_0292__mat__mat_NiZrCu_BDC | Nanosheet · Target Sample · Mixed Metal | washed five times with ethanol; dried at 60 Cabout 4 nm; about 6 layers | p002 · Results and Discussion · Figure 1e-g |
| NiZr-BDC catalyst electroderesearch_0292__mat__mat_NiZr_BDC | Electrode · Pristine Control · Composite | pristine_controlglassy carbon or FTO | p008 · Photoelectrochemical Performance |
| NiZr-BDC nanosheetsresearch_0292__mat__mat_NiZr_BDC | Nanosheet · Pristine Control · Mixed Metal | washed five times with ethanol; dried at 60 Cabout 5 nm | p002 · Results and Discussion · Figure 1c,d |
| Ni-BDC catalyst electroderesearch_0292__mat__mat_Ni_BDC | Electrode · Pristine Control · Composite | pristine_controlglassy carbon or FTO | p008 · Photoelectrochemical Performance |
| Ni-BDC nanosheetsresearch_0292__mat__mat_Ni_BDC | Nanosheet · Pristine Control · Pristine Framework | washed five times with ethanol; dried at 60 Cabout 5 nm | p002 · Results and Discussion · Figure 1a,b |