Synthesis · Ultra-thin Two-Dimensional Trimetallic Metal-Organic Framework for Photocatalytic Reduction of CO2

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

p008 · Experimental Section

Metal precursors116.3 mg Ni(NO3)2.6H2O; 35 mg ZrCl4; 48.3 mg Cu(NO3)2.3H2O

Linker precursors124.6 mg terephthalic acid

Solvents32 mL DMF; 2 mL ethanol

Additives0.8 mL TEA

Atmospherevented with nitrogen for 10 min, sealed

Temperatureroom temperature sonication; 60 C drying

Time8 h sonication

Work-upwashed five times with ethanol and dried in an oven at 60 C

Activationsorption samples degassed in vacuum at 300 C for 6 h; no synthesis activation stated

Scalability context100 mL beaker, room-temperature ultrasonic route

Show 8 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	terephthalic acid	124.6 mg	p008 · Experimental Section
Solvent	DMF	32 mL	p008 · Experimental Section
Solvent	ethanol	2 mL	p008 · Experimental Section
Metal Source	Ni(NO3)2.6H2O	116.3 mg	p008 · Experimental Section
Metal Source	ZrCl4	35 mg	p008 · Experimental Section
Metal Source	Cu(NO3)2.3H2O	48.3 mg	p008 · Experimental Section
Base	TEA	0.8 mL	p008 · Experimental Section
Other	nitrogen	10 min venting	p008 · Experimental Section

Complete recipeSource: Main

p008 · Experimental Section

Metal precursors174.5 mg Ni(NO3)2.6H2O; 35 mg ZrCl4

Linker precursors124.6 mg terephthalic acid

Solvents32 mL DMF; 2 mL ethanol

Additives0.8 mL TEA

Atmospherevented with nitrogen for 10 min, sealed

Temperatureroom temperature sonication; 60 C drying

Time8 h sonication

Work-upwashed five times with ethanol and dried in an oven at 60 C

Activationsorption samples degassed in vacuum at 300 C for 6 h; no synthesis activation stated

Scalability context100 mL beaker, room-temperature ultrasonic route

Show 7 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	terephthalic acid	124.6 mg	p008 · Experimental Section
Solvent	DMF	32 mL	p008 · Experimental Section
Solvent	ethanol	2 mL	p008 · Experimental Section
Metal Source	Ni(NO3)2.6H2O	174.5 mg	p008 · Experimental Section
Metal Source	ZrCl4	35 mg	p008 · Experimental Section
Base	TEA	0.8 mL	p008 · Experimental Section
Other	nitrogen	10 min venting	p008 · Experimental Section

Complete recipeSource: Main

p007 · Experimental Section

Metal precursors218.1 mg Ni(NO3)2.6H2O

Linker precursors124.6 mg terephthalic acid

Solvents32 mL DMF; 2 mL ethanol

Additives0.8 mL TEA

Atmospherevented with nitrogen for 10 min, sealed

Temperatureroom temperature sonication; 60 C drying

Time8 h sonication

Work-upwashed five times with ethanol and dried in an oven at 60 C

Activationsorption samples degassed in vacuum at 300 C for 6 h; no synthesis activation stated

Scalability context100 mL beaker, room-temperature ultrasonic route

Show 6 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	terephthalic acid	124.6 mg	p007 · Experimental Section
Solvent	DMF	32 mL	p007 · Experimental Section
Solvent	ethanol	2 mL	p007 · Experimental Section
Metal Source	Ni(NO3)2.6H2O	218.1 mg	p007 · Experimental Section
Base	TEA	0.8 mL	p007 · Experimental Section
Other	nitrogen	10 min venting	p007 · Experimental Section