Spectroscopy — Organic thermoelectric materials and devices based on p- and n-type poly(metal 1,1,2,2-ethenetetrathiolate)s

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

poly[Cux(Cu-ett)] black powder / compressed cuboid · Pellet

Cu 2p spectra for poly[Nax(Cu-ett)] and poly[Cux(Cu-ett)].

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu+ 2p3/2 peak	932.89 eV	—	—	Text Exact Reported	934 · XPS discussion · Figure S1b
Cu3+ 2p3/2 peak	934.58 eV	—	—	Text Exact Reported	934 · XPS discussion · Figure S1b
absence of CuII satellite	no typical configuration interaction satellite at 940-950 eV	—	—	Text Qualitative	934 · XPS discussion · Figure S1b

poly[Nax(Ni-ett)] black powder / compressed cuboid · Pellet

Ni 2p3/2 region in Figure S1a; main text reports peak assignments.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni 2p3/2 centre-metal peak	854.1 eV	—	—	Text Exact Reported	934 · XPS discussion · Figure S1a
Ni 2p3/2 counter-cation peak	855.7 eV	—	—	Text Exact Reported	934 · XPS discussion · Figure S1a
Ni coordination state	weak shake-up satellite around 860 eV suggests square-planar low-spin Ni	—	—	Qualitative Qualitative	934 · XPS discussion · Figure S1a