Electrochemistry Application — Bimetallic MOFs with tunable morphology: Synthesis and enhanced lithium storage properties

7 measurement groups · 26 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Co-Ni-MOF 1:1/carbon black/PVDF electrode · Electrode

Co-Ni-MOF 1:1 electrode, cycles 1, 2, 5, 10, 20 and 50 at 100 mA g-1.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Initial coulombic efficiency	64.9%	—	—	Text Exact Reported	5 · 3. Results and discussion · Fig. 4d
Initial charge capacity	1360.8 mA h g-1	—	—	Text Exact Reported	5 · 3. Results and discussion · Fig. 4d
Initial discharge capacity	2096.1 mA h g-1	—	—	Text Exact Reported	5 · 3. Results and discussion · Fig. 4d

Co-Ni-MOF 1:1/carbon black/PVDF electrode · Electrode

First cycle of Co-Ni-MOF 1:1 electrode.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
dQ/dV stepwise reduction and ligand reaction peaks	1.11, 0.74 and 0.035 V cathodic peaks ascribed to stepwise reduction of Co2+ to Co0, Ni2+ to Ni0 and reaction on unsaturated carbons of BDC ligands	—	around for 1.11, 0.74 and 0.035 V	Text Approximate	5 · 3. Results and discussion · Fig. 4e
dQ/dV cathodic SEI peak	1.17 V cathodic peak belongs to SEI layer formation	—	—	Text Exact Reported	5 · 3. Results and discussion · Fig. 4e

MOF/carbon black/PVDF electrode series · Electrode

CR2032 lithium half-cells, 0.01-3 V vs Li+/Li, 100 mA g-1, MOF/carbon black/PVDF electrodes.

Atmosphere: Ar-filled glovebox for cell assembly
Geometry: CR2032 coin cell with Li foil counter/reference electrode, Celgard 2400 separator, 1 M LiPF6 in EC/EMC/DMC
Context: composite electrode; pristine Ni-MOF electrode used as control
Measurement source: 2 · 2.3. Electrochemical measurements · Fig. 4a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-Ni-MOF 1:1 reversible discharge capacity after 100 cyclesMarked as a best value within this paper	800 mA h g-1 after 100 cycles at 100 mA g-1	—	—	Text Rounded Reported	1 · Abstract · Fig. 4a
Co-Ni-MOF 2:1 discharge capacity after 100 cycles	Co-Ni-MOF electrodes with molar ratio 2:1 and 1:1 reach 800 mA h g-1 after 100 cycles	—	—	Text Rounded Reported	5 · 3. Results and discussion · Fig. 4a
Ni-MOF control capacity after 100 cycles	302 mA h g-1	—	—	Text Exact Reported	5 · 3. Results and discussion · Fig. 4a
Co-Ni-MOF 1:1 capacity retention after 100 cyclesMarked as a best value within this paper	98% specific capacity retention after 100 cycles	—	—	Text Rounded Reported	1 · Abstract · Fig. 4a

Co-Ni-MOF 1:1/carbon black/PVDF electrode · Electrode

Co-Ni-MOF 1:1 electrode cycled for 500 cycles at 300, 500 and 1000 mA g-1 in Fig. 4f.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Approximate capacity after 500 cycles at 1000 mA g-1	about 110 mA h g-1 after 500 cycles at 1000 mA g-1, read from Fig. 4f	—	rough visual estimate, +/-40 mA h g-1	Visual Estimate Approximate	4 · Figure · Fig. 4f
Approximate capacity after 500 cycles at 300 mA g-1	about 220 mA h g-1 after 500 cycles at 300 mA g-1, read from Fig. 4f	—	rough visual estimate, +/-50 mA h g-1	Visual Estimate Approximate	4 · Figure · Fig. 4f

Co-Ni-MOF 1:1/carbon black/PVDF electrode · Electrode

Co-Ni-MOF 1:1 electrode before and after 100 cycles.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Post-cycling impedance increase	Charge-transfer and diffusion resistance increase after cycling.	—	—	Text Qualitative	5 · 3. Results and discussion · Fig. 5a
Post-cycling morphology change	MOF microspheres were broken into fine particles after cycling.	—	—	Text Qualitative	5 · 3. Results and discussion · Fig. 5b

Co-Ni-MOF 1:1/carbon black/PVDF electrode · Electrode

Co-Ni-MOF 1:1 electrode cycled at 100, 200, 300, 500 and 1000 mA g-1, then returned to 100 mA g-1.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-Ni-MOF 1:1 rate capacity at 100 mA g-1Marked as a best value within this paper	890 mA h g-1 at 100 mA g-1	—	—	Text Exact Reported	5 · 3. Results and discussion · Fig. 4c
Co-Ni-MOF 1:1 rate capacity at 1000 mA g-1	380 mA h g-1 at 1000 mA g-1	—	—	Text Exact Reported	1 · Abstract · Fig. 4c
Co-Ni-MOF 1:1 rate capacity at 200 mA g-1	770 mA h g-1 at 200 mA g-1	—	—	Text Exact Reported	5 · 3. Results and discussion · Fig. 4c
Co-Ni-MOF 1:1 rate capacity at 300 mA g-1	700 mA h g-1 at 300 mA g-1	—	—	Text Exact Reported	5 · 3. Results and discussion · Fig. 4c
Co-Ni-MOF 1:1 rate capacity at 500 mA g-1	600 mA h g-1 at 500 mA g-1	—	—	Text Exact Reported	1 · Abstract · Fig. 4c
Co-Ni-MOF 1:1 recovered capacity when returned to 100 mA g-1	860 mA h g-1 after current lowered to 100 mA g-1	—	—	Text Exact Reported	5 · 3. Results and discussion · Fig. 4c

Co-Ni-MOF 1:1/carbon black/PVDF electrode · Electrode

Co-Ni-MOF 'This work' row in SI Table S1; voltage window 0.01-3 V vs Li/Li+, 100-cycle performance, conversion/intercalation mechanism.

Geometry: Lithium-ion battery anode comparison table; electrode fabrication details in main text.
Context: composite electrode; SI summary row for this work
Measurement source: 2 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
SI Table S1 Co-Ni-MOF capacity at 100 mA g-1Marked as a best value within this paper	800/100	—	—	SI Table Exact Reported	2 · Table S1 · Table S1
SI Table S1 Co-Ni-MOF capacity at 1000 mA g-1	200/1000	—	—	SI Table Exact Reported	2 · Table S1 · Table S1
SI Table S1 Co-Ni-MOF capacity at 300 mA g-1	541/300	—	—	SI Table Exact Reported	2 · Table S1 · Table S1
SI Table S1 Co-Ni-MOF capacity at 500 mA g-1	371/500	—	—	SI Table Exact Reported	2 · Table S1 · Table S1
SI Table S1 cycling performance entry	100 cycles	—	—	SI Table Exact Reported	2 · Table S1 · Table S1
SI Table S1 lithium storage mechanism entry	Conversion/Intercalation	—	—	SI Table Qualitative	2 · Table S1 · Table S1
SI Table S1 voltage window for Co-Ni-MOF anode	0.01-3 V vs Li/Li+	—	range	SI Table Range	2 · Table S1 · Table S1