cMOF Evidence Base
Diffraction Structure — 2-Cyano-2-isonitrosoacetamide and its Ag(I) complexes. Silver(I) cyanoximate as a non-electric gas sensor

Measurement evidence

Diffraction Structure

2-Cyano-2-isonitrosoacetamide and its Ag(I) complexes. Silver(I) cyanoximate as a non-electric gas sensor · Gerasimchuk N., Esaulenko A.N., Dalley K.N. et al. · Dalton Transactions · 2010 · 749-764

4 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Single-crystal X-ray diffraction; Bruker APEX2, Mo Kalpha radiation

X-ray diffraction and scattering

solid complex 6 · Powder

Non-merohedral twin; data collected at 120 K with 120 s exposure per image; TWINABS absorption correction.

Temperature
120
Geometry
single-crystal thin plate
Context
pristine coordination polymer
Measurement source
p007 / SI p.7 · ESI S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Ag-Ag argentophilic distance in 6Marked as a best value within this paper3.1934(8) A—(8) ATable
Exact Reported		p005 / article p.753 · Table 3 · Table 3
unit-cell volume of 6508.6(2) A3—(2) A3Table
Exact Reported		p003 / article p.751 · Table 1 · Table 1
space group of 6P21/c——Table
Exact Reported		p003 / article p.751 · Table 1 · Table 1
complex 6 topologylayered 2D coordination polymer——Text
Qualitative		p007 / article p.755 · Crystal structure of 6 · Figure 3

Single-crystal X-ray diffraction; Bruker APEX2, Mo Kalpha radiation

X-ray diffraction and scattering

dark-yellow prisms of complex 7 · Single Crystal

Room-temperature data collection; triclinic P-1 structure.

Temperature
296
Geometry
single crystal
Context
monomeric related Ag cyanoximate
Measurement source
p003 / article p.751 · X-Ray crystallography · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
structure type of 7monomeric compound containing chelate anion 1-——Text
Qualitative		p006 / article p.754 · Results and discussion

Single-crystal X-ray diffraction; Bruker APEX2, Mo Kalpha radiation

X-ray diffraction and scattering

orange-yellow needles of complex 8 · Single Crystal

Room-temperature data collection; monoclinic polar P21 structure.

Temperature
293
Geometry
single crystal
Context
ionic ammine related Ag cyanoximate
Measurement source
p003 / article p.751 · X-Ray crystallography · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
N(4)-Ag(1)-N(5) angle in 8173.52(11) degrees—(11) degreesTable
Exact Reported		p005 / article p.753 · Table 5 · Table 5

Single-crystal X-ray diffraction; Bruker APEX2, Mo Kalpha radiation

X-ray diffraction and scattering

light-brown blocks of complex 9 · Single Crystal

Room-temperature data collection; monoclinic P21/n structure.

Temperature
290
Geometry
single crystal
Context
1D coordination polymer related Ag cyanoximate
Measurement source
p003 / article p.751 · X-Ray crystallography · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Ag-H-C agostic contact in 9Marked as a best value within this paper2.591 A——Caption
Exact Reported		p010 / article p.758 · Figure 8 caption · Figure 8
structure type of 9zigzag infinite coordination polymer of cationic [Ag(N4)]+ units——Text
Qualitative		p009 / article p.757 · Crystal structure of 9 · Scheme 3