cMOF Evidence Base
Electrical Transport — 2-Cyano-2-isonitrosoacetamide and its Ag(I) complexes. Silver(I) cyanoximate as a non-electric gas sensor

Measurement evidence

Electrical Transport

2-Cyano-2-isonitrosoacetamide and its Ag(I) complexes. Silver(I) cyanoximate as a non-electric gas sensor · Gerasimchuk N., Esaulenko A.N., Dalley K.N. et al. · Dalton Transactions · 2010 · 749-764

2 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

YSI Conductance-Resistance meter Model 34

0.001 M solution of complex 6 in anhydrous DMSO · Unknown

1 mM solution in anhydrous DMSO; standards included ammonium bromide, tetrabutylammonium bromide, tetraphenylphosphonium bromide and hydrazinium dichloride.

Temperature
296
Atmosphere
anhydrous DMSO solution
Geometry
solution conductance cell
Context
dissolved coordination polymer; not solid-state transport
Measurement source
p003 / article p.751 · Materials and physical measurements
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
conductivity of 0.001 M solution of 6 in DMSOMarked as a best value within this paper24.1 +/- 0.2 mS—+/- 0.2 mSText
Exact Reported		p011 / article p.759 · Solutions electrical conductivity of silver(I) complexes
solution dissociation of complexes 6, 7 and 8complete dissociation; loss of solid state structures and formation of 1:1 electrolytes——Text
Qualitative		p011 / article p.759 · Solutions electrical conductivity of silver(I) complexes
intrinsic conductivity of DMSO solvent0.5 +/- 0.1 mS—+/- 0.1 mSText
Exact Reported		p011 / article p.759 · Solutions electrical conductivity of silver(I) complexes
tetrabutylammonium bromide standard conductivity24.7 +/- 0.4 mS—+/- 0.4 mSText
Exact Reported		p011 / article p.759 · Solutions electrical conductivity of silver(I) complexes
tetraphenylphosphonium bromide standard conductivity21.2 +/- 0.2 mS—+/- 0.2 mSText
Exact Reported		p011 / article p.759 · Solutions electrical conductivity of silver(I) complexes

solution electrical conductivity in DMSO

Electrical conductivity

0.001 M solution of compound 5 in DMSO · Unknown

0.001 M DMSO solutions of compounds 4, 5, 6, 7, 8 and 9 compared qualitatively for dissociation behaviour.

Temperature
296
Atmosphere
DMSO solution
Geometry
solution conductance cell
Context
solution dissociation comparison
Measurement source
p011 / article p.759 · Solutions electrical conductivity of silver(I) complexes
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
partial ionisation of compound 4approximately 50% ionisation—approximatelyText
Approximate		p011 / article p.759 · Solutions electrical conductivity of silver(I) complexes
solution dissociation of compounds 5 and 9complete dissociation and formation of 1:1 electrolytes——Text
Qualitative		p011 / article p.759 · Solutions electrical conductivity of silver(I) complexes