Measurement evidence
Structure–Property Engineering of Redox-Active Tetrathiafulvalene- and Bipyridine-Based Metal–Organic Frameworks for Battery Cathodes · Wakamatsu K., Oshima H., Kobayashi N. et al. · Chemistry - A European Journal · 2026
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Cd2(TTFTB) MOF cathode · Electrode
HZ-Pro S12; 1.5-4.2 V vs Li+/Li; 10 mV s^-1; RT
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| LIB CV charging peaks | approximately 3.4-4.0 V | — | — | Text Range | S9 · Figure S9d-e |
| LIB CV discharging peaks | approximately 3.3-3.7 V | — | — | Text Range | S9 · Figure S9d-e |
TTF-hybrid-MOF cathode · Electrode
HZ-Pro S12; 1.5-4.2 V vs Li+/Li; 10 mV s^-1; RT
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|
Cd2(TTFTB) MOF cathode · Electrode
HZ-Pro S12; 1.0-4.2 V vs Na+/Na; 10 mV s^-1; RT
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| SIB CV TTF charging peaks | 3.2-4.0 V | — | — | Text Range | 5 · Figure 3d-e |
| SIB CV TTF discharging peaks | approximately 2.8-3.5 V | — | — | Text Range | 5 · Figure 3d-e |
TTF-hybrid-MOF cathode · Electrode
HZ-Pro S12; 1.0-4.2 V vs Na+/Na; 10 mV s^-1; RT
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| SIB hybrid bipyridine CV charging peaks | 2.0-2.9 V | — | — | Text Range | 5 · Figure 3e |
| SIB hybrid bipyridine CV discharge peaks | approximately 1.2-2.1 V | — | — | Text Range | 5 · Figure 3e |
TTF-hybrid-MOF cathode · Electrode
Powder: 0.002 g in 2 mL electrolyte, sonicate 30 s, store RT 1 day. Electrode pieces: immersed in 2 mL electrolyte for 1, 3, 5, and 7 days.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| relative electrolyte dissolution | Cd2(TTFTB) and TTF-hybrid-MOF lower solubility than H4TTFTB and bpea in both SIB and LIB electrolytes | — | — | Text Qualitative | 7 · Figures S12-S13 |
Cd2(TTFTB) MOF cathode · Electrode
HZ-Pro S12; 100 kHz to 10 mHz; RT; WE-RE; ZView equivalent-circuit fitting
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Rct fitted impedance | 469.50 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
| Rs fitted impedance | 19.07 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
| Wo fitted impedance | 164.90 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
TTF-hybrid-MOF cathode · Electrode
HZ-Pro S12; 100 kHz to 10 mHz; RT; WE-RE; ZView equivalent-circuit fitting
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Rct fitted impedance | 68.43 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
| Rs fitted impedance | 2.61 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
| Wo fitted impedance | 54.64 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
Cd2(TTFTB) MOF cathode · Electrode
HZ-Pro S12; 100 kHz to 10 mHz; RT; WE-RE; ZView equivalent-circuit fitting
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Rct fitted impedance | 229.20 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
| Rs fitted impedance | 70.13 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
| Wo fitted impedance | 203.60 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
TTF-hybrid-MOF cathode · Electrode
HZ-Pro S12; 100 kHz to 10 mHz; RT; WE-RE; ZView equivalent-circuit fitting
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Rct fitted impedanceMarked as a best value within this paper | 69.02 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
| Rs fitted impedance | 111.60 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
| Wo fitted impedanceMarked as a best value within this paper | 54.77 ohm | — | — | SI Table Exact Reported | S40 · Table S3 |
Cd2(TTFTB) MOF cathode · Electrode
CR2032 Li cell; 1.0 M LiPF6 in EC/DEC (1:1); 1.5-4.2 V vs Li+/Li; 100 mA g^-1; RT; charging first
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| LIB 200th-cycle discharge capacity | 46 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB 30th-cycle discharge capacity | 62 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB maximum discharge capacity | 89 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB 200th-cycle capacity retention | 52% | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB one-electron theoretical capacity | 29 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB TTF charge plateau range | ~3.3-4.0 V | — | — | Text Range | S7 · Figure S9a-b |
| LIB TTF discharge plateau range | ~3.2-3.8 V | — | — | Text Range | S7 · Figure S9a-b |
H4TTFTB ligand cathode · Electrode
Literature H4TTFTB control under same 100 mA g^-1 LIB comparison
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| LIB 200th-cycle discharge capacity | 31 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB 30th-cycle discharge capacity | 42 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB maximum discharge capacity | 279 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB 200th-cycle capacity retention | 11% | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB one-electron theoretical capacity | 39 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
TTF-hybrid-MOF cathode · Electrode
CR2032 Li cell; 1.0 M LiPF6 in EC/DEC (1:1); 1.5-4.2 V vs Li+/Li; 100 mA g^-1; RT; charging first
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| LIB 200th-cycle discharge capacity | 68 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB 30th-cycle discharge capacity | 85 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB maximum discharge capacityMarked as a best value within this paper | 130 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB 200th-cycle capacity retention | 53% | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB one-electron theoretical capacity | 26 mAh/g | — | — | SI Table Exact Reported | S39 · Table S2 |
| LIB hybrid bipyridine-derived charge plateau | approximately 2.0-3.0 V | — | — | Text Range | S7 · Figure S9b |
| LIB hybrid bipyridine-derived discharge plateau | approximately 1.7-2.4 V | — | — | Text Range | S7 · Figure S9b |
Cd2(TTFTB) MOF cathode · Electrode
CR2032 Na cell; 1.0 M NaClO4 in EC/PC (1:1); 1.0-4.2 V vs Na+/Na; 100 mA g^-1; RT; charging first
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| SIB 200th-cycle discharge capacity | 110 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB 30th-cycle discharge capacity | 130 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB maximum discharge capacity | 151 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB 200th-cycle capacity retention | 73% | — | — | Table Exact Reported | 5 · Table 1 |
| SIB one-electron theoretical capacity | 29 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB TTF charge plateau range | 3.2-3.9 V | — | — | Text Range | 3 · Figure 3a-b |
| SIB TTF discharge plateau range | 3.0-3.5 V | — | — | Text Range | 3 · Figure 3a-b |
H4TTFTB ligand cathode · Electrode
Literature H4TTFTB control under same 100 mA g^-1 SIB comparison
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| SIB 200th-cycle discharge capacity | 66 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB 30th-cycle discharge capacity | 69 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB maximum discharge capacity | 179 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB 200th-cycle capacity retention | 37% | — | — | Table Exact Reported | 5 · Table 1 |
| SIB one-electron theoretical capacity | 39 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
TTF-hybrid-MOF cathode · Electrode
CR2032 Na cell; 1.0 M NaClO4 in EC/PC (1:1); 1.0-4.2 V vs Na+/Na; 100 mA g^-1; RT; charging first
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| SIB 200th-cycle discharge capacity | 121 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB 30th-cycle discharge capacity | 144 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB maximum discharge capacityMarked as a best value within this paper | 220 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB 200th-cycle capacity retention | 55% | — | — | Table Exact Reported | 5 · Table 1 |
| SIB one-electron theoretical capacity | 26 mAh/g | — | — | Table Exact Reported | 5 · Table 1 |
| SIB hybrid bipyridine-derived charge plateau | approximately 2.0-2.8 V | — | — | Text Range | 3 · Figure 3b |
| SIB hybrid bipyridine-derived discharge plateau | approximately 1.2-2.1 V | — | — | Text Range | 3 · Figure 3b |
TTF-hybrid-MOF cathode · Electrode
HJ1020mSD8; current sequence 50, 100, 500, 1000, 50 mA g^-1; five cycles each; 1.5-4.2 V vs Li+/Li; RT
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| visual rate-capability discharge capacity at 1000 mA/g | Cd2(TTFTB) about 25 mAh/g at 1000 mA/g in LIB | — | — | Visual Estimate Approximate | S22 · Figure S9f |
| visual rate-capability discharge capacity at 1000 mA/g | TTF-hybrid-MOF about 40 mAh/g at 1000 mA/g in LIB | — | — | Visual Estimate Approximate | S22 · Figure S9f |
TTF-hybrid-MOF cathode · Electrode
HJ1020mSD8; current sequence 50, 100, 500, 1000, 50 mA g^-1; five cycles each; 1.0-4.2 V vs Na+/Na; RT
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| visual rate-capability discharge capacity at 1000 mA/g | Cd2(TTFTB) about 70 mAh/g at 1000 mA/g in SIB | — | — | Visual Estimate Approximate | 4 · Figure 3f |
| visual rate-capability discharge capacity at 1000 mA/g | TTF-hybrid-MOF about 95 mAh/g at 1000 mA/g in SIB | — | — | Visual Estimate Approximate | 4 · Figure 3f |