Synthesis evidence

Novel semiconducting metal-organic framework: Synthesis, structural characterisation and electrical conductivity studies of manganese based two dimensional coordination polymer

Karthikeyan M., Bhagyaraju B., Mariappan C.R. et al. · Inorganic Chemistry Communications · 2012 · 269-272

1 structured synthesis route

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Other

272 · Reference note [12]

Metal precursorsmanganese chloride tetra hydrate, 395.8 mg, 2 mmol
Linker precursorspyrazine, 160 mg, 2 mmol
Solventsdistilled water, 2 ml; ethanol-water mixture, 2 ml
AtmosphereAmbient atmosphere; not otherwise controlled
Temperatureambient temperature
Time168
Work-upCrystals were washed with distilled water and ethanol, filtered and dried in vacuum.
ActivationVacuum drying after filtration; no separate activation reported.
Scalability contextSmall-batch ambient crystallisation; isolated yield 520 mg (95%).
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcemanganese chloride tetra hydrate395.8 mg, 2 mmol · in distilled water (2 ml)272 · Reference note [12]
Linkerpyrazine160 mg, 2 mmol · in ethanol-water mixture (2 ml)272 · Reference note [12]
Solventdistilled water2 ml272 · Reference note [12]
Solventethanol-water mixture2 ml · ethanol:water ratio not reported272 · Reference note [12]