cMOF Evidence Base
Other — Semiconducting lanthanide polymers of pyridine-2,6-dicarboxylate: Hydrothermal synthesis, structural characterization, electrical conductivity and luminescence properties

Measurement evidence

Other

Semiconducting lanthanide polymers of pyridine-2,6-dicarboxylate: Hydrothermal synthesis, structural characterization, electrical conductivity and luminescence properties · Ay B., Yildiz E., Kani I. · Polyhedron · 2018 · 1-8

4 measurement groups · 46 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Solubility test in common organic and inorganic solvents.

compound 1 colourless crystals · Single Crystal

Rendered SI Table S1 lists water, methanol, ethanol, acetone, DMSO, diethylether, chloroform, hexane, DMF, DCM, THF, ethyl acetate, benzene, heptane, propanol, acetonitrile, butanol, toluene, and chloroform:methanol:water; i = insoluble.

Context
pristine framework
Measurement source
7 · Supplementary Information · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
solubility in common organic and inorganic solventsinsoluble——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Acetonei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Acetonitrilei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Benzenei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Butanoli (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Chloroformi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Chloroform:Methanol:Wateri (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in DCMi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Dietyletheri (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in DMFi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in DMSOi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Ethanoli (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Ethyl acetatei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Heptanei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Hexanei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Methanoli (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Propanoli (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in THFi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Toluenei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Wateri (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1

Thermogravimetric analysis using Perkin Elmer Pyris Diamond TG/DTA.

Calorimetry and thermal analysisThermogravimetric analysis

compound 1 colourless crystals · Single Crystal

50-900 C under N2, heating rate 10 C min^-1; single crystals selected under optical microscope.

Atmosphere
N2
Geometry
single crystals
Context
pristine framework
Measurement source
5 · 3.3. Thermal analysis and PXRD patterns · Fig. S6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
third TGA weight loss61.43% from 407 C to 590 C61.43 %—Text
Exact Reported		5 · 3.3. Thermal analysis and PXRD patterns · Fig. S6
first and second TGA weight loss10.23% from 146 C to 380 C10.23 %—Text
Exact Reported		5 · 3.3. Thermal analysis and PXRD patterns · Fig. S6
thermal stability limitthermally stable up to approximately 145 C418.15 KapproximatelyText
Approximate		5 · 3.3. Thermal analysis and PXRD patterns · Fig. S6

Solubility test in common organic and inorganic solvents.

compound 2 violet crystals · Single Crystal

Rendered SI Table S1 lists water, methanol, ethanol, acetone, DMSO, diethylether, chloroform, hexane, DMF, DCM, THF, ethyl acetate, benzene, heptane, propanol, acetonitrile, butanol, toluene, and chloroform:methanol:water; i = insoluble.

Context
pristine framework
Measurement source
7 · Supplementary Information · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
solubility in common organic and inorganic solventsinsoluble——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Acetonei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Acetonitrilei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Benzenei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Butanoli (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Chloroformi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Chloroform:Methanol:Wateri (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in DCMi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Dietyletheri (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in DMFi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in DMSOi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Ethanoli (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Ethyl acetatei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Heptanei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Hexanei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Methanoli (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Propanoli (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in THFi (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Toluenei (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1
solubility in Wateri (insoluble)——SI Table
Qualitative		7 · Supplementary Information · Table S1

Thermogravimetric analysis using Perkin Elmer Pyris Diamond TG/DTA.

Calorimetry and thermal analysisThermogravimetric analysis

compound 2 violet crystals · Single Crystal

50-900 C under N2, heating rate 10 C min^-1; single crystals selected under optical microscope.

Atmosphere
N2
Geometry
single crystals
Context
pristine framework
Measurement source
5 · Supplementary Information · Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
last TGA weight loss63.06% from 420 C to 600 C63.06 %—Text
Exact Reported		6 · 3.3. Thermal analysis and PXRD patterns · Fig. S7
first and second TGA weight loss9.02% from 151 C to 390 C9.02 %—Text
Exact Reported		6 · 3.3. Thermal analysis and PXRD patterns · Fig. S7
thermal stability limitthermally stable up to approximately 145 C418.15 KapproximatelyText
Approximate		5 · 3.3. Thermal analysis and PXRD patterns · Fig. S7