Spectroscopy — Semiconducting lanthanide polymers of pyridine-2,6-dicarboxylate: Hydrothermal synthesis, structural characterization, electrical conductivity and luminescence properties

Measurement evidence

Spectroscopy

Semiconducting lanthanide polymers of pyridine-2,6-dicarboxylate: Hydrothermal synthesis, structural characterization, electrical conductivity and luminescence properties · Ay B., Yildiz E., Kani I. · Polyhedron · 2018 · 1-8

4 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FT-IR spectroscopy with KBr pellets on Perkin-Elmer RX-1.

compound 1 colourless crystals · Single Crystal

4000-400 cm^-1 spectral range.

Geometry
KBr pellet
Context
pristine framework
Measurement source
2 · 2.1. Materials and methods
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
La-N stretching band521 cm^-1521 cm^-1Text
Exact Reported
5 · 3.2. FT-IR spectra
La-O stretching band417 cm^-1417 cm^-1Text
Exact Reported
5 · 3.2. FT-IR spectra
N-H stretching band3640 cm^-13640 cm^-1Text
Exact Reported
5 · 3.2. FT-IR spectra · Fig. S4

Solid-state photoluminescence spectroscopy using Perkin-Elmer LS 55 Luminescence Spectrometer.

compound 1 colourless crystals · Single Crystal

Room-temperature solid-state emission; excitation at 320 nm.

Temperature
room temperature
Atmosphere
air/ambient not explicitly specified
Geometry
solid state
Context
pristine framework
Measurement source
7 · 3.5. Photoluminescence properties · Fig. 7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
maximum photoluminescence emission612 nm upon excitation at 320 nm612 nmText
Rounded Reported
7 · 3.5. Photoluminescence properties · Fig. 7

FT-IR spectroscopy with KBr pellets on Perkin-Elmer RX-1.

compound 2 violet crystals · Single Crystal

4000-400 cm^-1 spectral range.

Geometry
KBr pellet
Context
pristine framework
Measurement source
3 · Supplementary Information · Figure S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Nd-N stretching band525 cm^-1525 cm^-1Text
Exact Reported
5 · 3.2. FT-IR spectra
Nd-O stretching band419 cm^-1419 cm^-1Text
Exact Reported
5 · 3.2. FT-IR spectra
N-H stretching band3645 cm^-13645 cm^-1Text
Exact Reported
5 · 3.2. FT-IR spectra · Fig. S5

Solid-state photoluminescence spectroscopy using Perkin-Elmer LS 55 Luminescence Spectrometer.

compound 2 violet crystals · Single Crystal

Room-temperature solid-state emission; excitation at 320 nm.

Temperature
room temperature
Atmosphere
air/ambient not explicitly specified
Geometry
solid state
Context
pristine framework
Measurement source
7 · 3.5. Photoluminescence properties · Fig. 7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
maximum photoluminescence emission624 nm upon excitation at 320 nm624 nmText
Rounded Reported
7 · 3.5. Photoluminescence properties · Fig. 7