Synthesis evidence

Two-Dimensional Electrically Conductive Metal-Organic Framework Boosts Synaptic Plasticity for Dynamic Image Refresh, Classification, and Efferent Neuromuscular Systems

Wei H., Liu J., Ni Y. et al. · Nano Letters · 2024 · 15379-15387

4 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: SI

Route 1: Air Liquid Interface

p002 · Experimental Section - Synthesis of EC-MOF film · Figure S2

Metal precursorsNi(NO3)2.6H2O, 15 mg (0.052 mmol)
Linker precursorsHAB.3HCl, 5 mg (0.109 mmol)
SolventsDegassed water: 8 mL for Ni salt solution and 8 mL for HAB.3HCl solution
AdditivesEthylenediamine, 10 uL
AtmosphereSolutions mixed in an O2-free acrylic isolation glovebox; sealed Petri dish/plastic container then transferred to ambient environment
Temperatureambient
Time12
Substrate orientationFilm formed at air/liquid surface and transferred to prepared silicon wafer substrate
Oxidant / reductantOxidation indicated schematically in Figure S2; no separate oxidant amount reported
Work-upTransferred film to silicon wafer; water residue removed by natural drying in air
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceNi(NO3)2.6H2O15 mg (0.052 mmol)p002 · Experimental Section - Synthesis of EC-MOF film · Figure S2
LinkerHAB.3HCl5 mg (0.109 mmol)p002 · Experimental Section - Synthesis of EC-MOF film · Figure S2
Solventdegassed water8 mL + 8 mLp002 · Experimental Section - Synthesis of EC-MOF film · Figure S2
Baseethylenediamine10 uLp002 · Experimental Section - Synthesis of EC-MOF film · Figure S2
Partial recipeSource: SI

Route 2: Drop Cast

p002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1

Metal precursorsPreformed Ni-HAB EC-MOF film
SolventsGlacial acetic acid solution, 4.0 mL
AdditivesChitosan powder, 60.0 mg; glycerol, 0.2 mL
AtmosphereNot reported for electrolyte deposition
Temperature90
Time0.333
Substrate orientationProton-type solution dropped on top of EC-MOF film; dot electrodes cast through mask
Work-upAnnealed at 90 C for 20 min; dot electrodes cast with aid of mask
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Electrolytechitosan powder60.0 mgp002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1
Additiveglycerol0.2 mLp002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1
Acidglacial acetic acid solution4.0 mLp002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1
Partial recipeSource: SI

Route 3: Drop Cast

p002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1

Metal precursorsPreformed Ni-HAB EC-MOF film
SolventsAcetonitrile, 30.0 mL
AdditivesLiClO4, 1.5 mmol; PEO powder, amount not reported
AtmosphereNot reported for electrolyte deposition
Temperature90
Time0.333
Substrate orientationElectrolyte gel dropped on top of EC-MOF film; dot electrodes cast through mask
Work-upAnnealed at 90 C for 20 min; dot electrodes cast with aid of mask
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
ElectrolyteLiClO41.5 mmolp002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1
AdditivePEO powdersnot reportedp002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1
Solventacetonitrile30.0 mLp002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1
Partial recipeSource: SI

Route 4: Drop Cast

p002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1

Metal precursorsPreformed Ni-HAB EC-MOF film
SolventsAcetonitrile, 30.0 mL
AdditivesNaClO4, 1.5 mmol; PEO powder, amount not reported
AtmosphereNot reported for electrolyte deposition
Temperature90
Time0.333
Substrate orientationElectrolyte gel dropped on top of EC-MOF film; dot electrodes cast through mask
Work-upAnnealed at 90 C for 20 min; dot electrodes cast with aid of mask
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
ElectrolyteNaClO41.5 mmolp002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1
AdditivePEO powdersnot reportedp002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1
Solventacetonitrile30.0 mLp002 · Experimental Section - Fabrication of electrolytes and devices · Figure S1