Computational Modelling — Vapor-Induced Superionic Conduction of Magnesium Ions in a Metal-Organic Framework

Measurement evidence

Computational Modelling

Vapor-Induced Superionic Conduction of Magnesium Ions in a Metal-Organic Framework · Yoshida Y., Kato K., Sadakiyo M. · Journal of Physical Chemistry C · 2021 · 21124-21130

1 measurement group · 1 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Simple density-functional theory calculation of guest molecular size and dipole moment; Gaussian03, B3LYP/6-31G(d)

Mg-MOF-74 superset {Mg(TFSI)2}0.15 · Powder

Guest vapour parameters compiled for MeOH, EtOH, MeCN, THF, PC, and DEC.

Geometry
molecular model parameters
Context
guest-size comparison for vapour-induced conductivity
Measurement source
p004 / article p.21127 · Ionic Conductivity and Mg2+ Transport · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Guest molecular size trend used to rationalise conductivityMeOH 4.5 x 4.2 A; EtOH 5.8 x 4.4 A; MeCN 5.8 x 4.2 A; THF 5.8 x 6.0 A; PC 8.4 x 6.7 A; DEC 10.7 x 5.6 ATable
Exact Reported
p004 / article p.21127 · Ionic Conductivity and Mg2+ Transport · Table 1