Porosity

N2 adsorption isotherms at 77 K, BELSORP-max; BET surface area

Mg-MOF-74 superset {Mg(TFSI)2}x loading series · Powder

Samples completely dehydrated under vacuum at 130 deg C before N2 adsorption.

Temperature: 77
Atmosphere: N2
Geometry: powder adsorption
Context: x = 0, 0.07, 0.13, and 0.15 salt-loading series
Measurement source: p003 / article p.21126 · Results and Discussion - Preparation of Mg-Included MOF · Figure 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area, x = 0 blank Mg-MOF-74Marked as a best value within this paper	769 m2 g-1	769 m2 g-1	—	Text Exact Reported	p003 / article p.21126 · Results and Discussion - Preparation of Mg-Included MOF · Figure 2
BET surface area, x = 0.07	476 m2 g-1	476 m2 g-1	—	Text Exact Reported	p003 / article p.21126 · Results and Discussion - Preparation of Mg-Included MOF · Figure 2
BET surface area, x = 0.13	173 m2 g-1	173 m2 g-1	—	Text Exact Reported	p003 / article p.21126 · Results and Discussion - Preparation of Mg-Included MOF · Figure 2
BET surface area, x = 0.15	16 m2 g-1	16 m2 g-1	—	Text Exact Reported	p003 / article p.21126 · Results and Discussion - Preparation of Mg-Included MOF · Figure 2

Organic vapour adsorption isotherms at 298 K, BELSORP-max

Gas sorption and porosity

Mg-MOF-74 superset {Mg(TFSI)2}0.15 · Powder

MeOH and MeCN adsorption isotherms measured for x = 0 and x = 0.15 at 298 K; DEC adsorption also discussed. Samples dried under vacuum at 130 deg C overnight before measurements.

Temperature: 298
Atmosphere: MeOH vapour; MeCN vapour; DEC vapour
Geometry: powder adsorption
Context: x = 0 and x = 0.15 samples compared
Measurement source: p006 / article p.21129 · Adsorption Behavior for the Guest Vapors · Figure 6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DEC adsorption for x = 0 and x = 0.15	almost no adsorption of DEC	—	—	Text Qualitative	p009 / SI p.S9 · Adsorption Behavior for the Guest Vapors · Figure S14
Final MeCN adsorption amount for x = 0.15	finally reached 3.1 molecules	3.1 molecules per formula	—	Text Rounded Reported	p006 / article p.21129 · Adsorption Behavior for the Guest Vapors · Figure S13
MeCN molecules adsorbed per formula around 0.1 P/P0 for x = 0.15	1.1 molecules at around 0.1 P/P0	1.1 molecules per formula	around	Text Approximate	p006 / article p.21129 · Adsorption Behavior for the Guest Vapors · Figure S13
Final MeOH adsorption amount for x = 0.15Marked as a best value within this paper	finally reached 4.9 molecules	4.9 molecules per formula	—	Text Rounded Reported	p006 / article p.21129 · Adsorption Behavior for the Guest Vapors · Figures S12
MeOH molecules adsorbed per formula below 0.1 P/P0 for x = 0.15	around 2.5 MeOH molecules per formula below 0.1 P/P0	2.5 molecules per formula	around	Text Approximate	p006 / article p.21129 · Adsorption Behavior for the Guest Vapors · Figures S12

2 measurement groups · 9 results