cMOF Evidence Base
Diffraction Structure — Electrochemical properties of uniquely structured Fe2O3 and FeSe2/graphitic-carbon microrods synthesized by applying a metal-organic framework

Measurement evidence

Diffraction Structure

Electrochemical properties of uniquely structured Fe2O3 and FeSe2/graphitic-carbon microrods synthesized by applying a metal-organic framework · Park S.-K., Kim J.K., Kang Y.C. · Chemical Engineering Journal · 2018 · 2440-2449

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

SEM, TEM, HR-TEM, SAED, elemental mapping, XRD

X-ray diffraction and scatteringScanning electron microscopyTransmission electron microscopyElemental microanalysis and mapping

H-Fe2O3-NSA microrods · Powder

H-Fe2O3-NSA after oxidation of Fe@GC at 300 deg C in air

Atmosphere
air oxidation product
Context
target derived LIB anode
Measurement source
p004-p005 / journal p2443-p2444 · Results & discussion · Fig. 2; Fig. S2b referenced
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
HR-TEM d-spacing assigned to hexagonal Fe2O3 (012)0.37 nm——Text
Exact Reported		p003 / journal p2442 · Results & discussion · Fig. 2e
HR-TEM d-spacing assigned to hexagonal Fe2O3 (018)0.16 nm——Text
Exact Reported		p003 / journal p2442 · Results & discussion · Fig. 2e
HR-TEM d-spacing assigned to hexagonal Fe2O3 (110)0.25 nm——Text
Exact Reported		p003 / journal p2442 · Results & discussion · Fig. 2e
phase assignmenthexagonal Fe2O3 phase (ICDD #33-0664)——Text
Qualitative		p003 / journal p2442 · Results & discussion · Fig. S2b referenced

SEM, TEM, HR-TEM, SAED, elemental mapping, XRD

X-ray diffraction and scatteringScanning electron microscopyTransmission electron microscopyElemental microanalysis and mapping

H-FeSe2/GC microrods · Powder

H-FeSe2/GC after selenization of Fe@GC at 250 deg C under H2/Ar

Atmosphere
post-selenization; surface oxidation/SeO2 impurities noted from handling
Context
target FeSe2/graphitic-carbon SIB anode
Measurement source
p006 / journal p2445 · Results & discussion · Fig. 3; Fig. S8 referenced
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
HR-TEM d-spacing assigned to orthorhombic FeSe2 (101)0.29 nm——Text
Exact Reported		p006 / journal p2445 · Results & discussion · Fig. 3e

SEM, TEM, XRD, N2 BET

X-ray diffraction and scatteringScanning electron microscopyTransmission electron microscopyGas sorption and porosity

MIL-88 microrods · Powder

MIL-88 precursor morphology, phase, and surface area; XRD and BET details primarily in SI figures referenced from main text

Context
pristine MOF precursor/control
Measurement source
p002 and p006 / SI S-2 and S-6 · Supporting Information · Figs. S1 and S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area157.7 m2 g-1——Text
Exact Reported		p005 / journal p2444 · Results & discussion · Fig. S7 referenced
MIL-88 microrod diameterabout 2 um——Text
Approximate		p003 / journal p2442 · Results & discussion · Fig. S1 referenced