Synthesis evidence

Metal-Organic Framework-Based Tribovoltaic Textile for Human Body Signal Monitoring

Li Y., Wu Y., Shokurov A.V. et al. · Advanced Science · 2025 · 2414086

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Both

Route 1: Other

SI text · Experimental Section/Methods - Synthesis of Cu-BHT

Metal precursorsCuCl2 dissolved in DI water to yield different concentration Cu ion solutions; 70 wt.% CuCl2 selected for further investigation
Linker precursorsBHT dissolved in chlorobenzene to form a 0.5 mM BHT solution
SolventsDI water; chlorobenzene; ethanol wash; DI water wash
Additives10 wt% NaOH for cotton desizing and cleaning
Atmosphereair / fume hood drying; no inert atmosphere reported
TimeNaOH pretreatment overnight; Cu ion soak 4 h; BHT reaction 0.5 h
Substrate orientationcotton textile immersed/soaked; BHT solution applied to cover Cu-cotton samples
Work-upAir-dried in a fume hood after Cu soak; after BHT reaction washed with EtOH and DI water.
Scalability contextSimple modification of common fabrics by soaking/coating; volumes, fabric size, and exact CuCl2 solution concentrations for each sample are not fully specified.
Show 6 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCopper chloride (CuCl2)different concentration Cu ions solution; 70 wt.% selected in main textSI text · Experimental Section/Methods - Synthesis of Cu-BHT
Linker1,2,3,4,5,6-benzenehexathiol (BHT)0.5 mM in chlorobenzeneSI text · Experimental Section/Methods - Synthesis of Cu-BHT
Solventchlorobenzene (CB)Not specifiedSI text · Experimental Section/Methods - Synthesis of Cu-BHT
Solventdeionized water (DI water)Not specifiedSI text · Experimental Section/Methods - Synthesis of Cu-BHT
BaseNaOH10 wt%SI text · Experimental Section/Methods - Synthesis of Cu-BHT
SolventEthanol (EtOH)wash solventSI text · Experimental Section/Methods - Synthesis of Cu-BHT
Partial recipeSource: SI

Route 2: Other

SI text · Experimental Section/Methods - Device fabrication and integration

Metal precursorsAluminium fabric (EGLA200 AL)
Linker precursorsCu-BHT cotton component
Additivesconductive fabric traces for wearable integrations; cushioning sponge for belt device
Substrate orientationCu-BHT cotton and Al fabric assembled as contacting/sliding textile layers
Scalability contextDevice assembly is textile sewing/affixing rather than a complete chemical recipe; exact device dimensions are not fully specified except 9 cm2 slider area for typical tests.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherAluminum fabric (EGLA200 AL)Not specifiedSI text · Experimental Section/Methods - Device fabrication and integration
OtherCu-BHT cottonNot specifiedSI text · Experimental Section/Methods - Device fabrication and integration
Otherconductive fabricNot specifiedSI text · Experimental Section/Methods - Device fabrication and integration
Vague recipeSource: Both

Route 3: Other

p005 · Results and Discussion · Figure S14

Metal precursorsCuCl2 / Cu ion solution, assumed same in situ Cu-BHT growth process
Linker precursorsBHT in chlorobenzene
SolventsDI water; chlorobenzene; ethanol and DI water wash
Additives10 wt% NaOH pretreatment likely for cotton fabrics; exact pretreatment for linen/blend not separately specified
Atmosphereair / fume hood drying; no inert atmosphere reported
Timesame route likely as Cu-BHT cotton; exact times not restated for alternative fabrics
Substrate orientationknitted 100% cotton, 97% cotton + 3% Lycra blend, and linen fabrics
Work-upwashed with EtOH and DI water in general Cu-BHT textile recipe
Scalability contextMain text states Cu-BHT was grown on other fabrics with similar output, but does not provide a separate full recipe for each substrate.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCopper chloride (CuCl2)Not specifiedp005 · Results and Discussion · Figure S14
Linker1,2,3,4,5,6-benzenehexathiol (BHT)0.5 mM in chlorobenzene in the general recipep005 · Results and Discussion · Figure S14
Solventchlorobenzene (CB)Not specifiedp005 · Results and Discussion · Figure S14
Solventdeionized water (DI water)Not specifiedp005 · Results and Discussion · Figure S14
SolventEthanol (EtOH)wash solventp005 · Results and Discussion · Figure S14