cMOF Evidence Base

Synthesis evidence

Highly Conductive Two-Dimensional Metal-Organic Frameworks for Resilient Lithium Storage with Superb Rate Capability

Wu Z., Adekoya D., Huang X. et al. · ACS Nano · 2020 · 12016-12026

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Other

p008 / 12023 · Material Characterization

Solventsdichloromethane
Atmospherevacuum drying after solvent exchange
Temperature50
Time72 h solvent exchange plus 12 h drying
Work-upsoaked in dichloromethane for 3 days; solvent changed every 24 h
Activationdried at 50 deg C for 12 h under vacuum
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
SolventdichloromethaneNot specifiedp008 / 12023 · Material Characterization
Partial recipeSource: Main

Route 2: Drop Cast

p008 / 12023 · Cell Configuration and Electrochemical Measurement

SolventsNMP
Additivescommercial multiwall CNTs; PVDF binder
Atmospherecoin cells assembled in Ar glovebox with H2O and O2 <1.0 ppm
Temperature60
Time12
Substrate orientationAl foil current collector
Work-upslurry ground in pestle for over 30 min, uniformly coated onto Al foils
Activationdried in a vacuum oven at 60 deg C for 12 h
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Otheras-prepared Cu-BHT samples70 wt% of electrode solidsp008 / 12023 · Cell Configuration and Electrochemical Measurement
Additivecommercial multiwall CNTs20 wt% of electrode solidsp008 / 12023 · Cell Configuration and Electrochemical Measurement
AdditivePVDF binder10 wt% of electrode solidsp008 / 12023 · Cell Configuration and Electrochemical Measurement
SolventNMPNot specifiedp008 / 12023 · Cell Configuration and Electrochemical Measurement
Electrolyte1 M LiTFSI in DOL/DME (1:1, v/v)1 Mp008 / 12023 · Cell Configuration and Electrochemical Measurement
Partial recipeSource: Main

Route 3: Drop Cast

p008 / 12023 · Cell Configuration and Electrochemical Measurement

SolventsNMP
AdditivesCNTs; PVDF binder
Atmospherecoin cells assembled in Ar glovebox with H2O and O2 <1.0 ppm
Temperature60
Time12
Substrate orientationAl foil current collector
Work-upslurry coating route analogous to 70:20:10 electrodes
Activationvacuum oven drying at 60 deg C for 12 h
Scalability contextUsed for higher active material loading and practical energy-density tests.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherCu-BHT active material90 wt% of electrode solidsp008 / 12023 · Cell Configuration and Electrochemical Measurement
AdditiveCNTs5 wt% of electrode solidsp008 / 12023 · Cell Configuration and Electrochemical Measurement
AdditivePVDF binder5 wt% of electrode solidsp008 / 12023 · Cell Configuration and Electrochemical Measurement
Partial recipeSource: SI

Route 4: Drop Cast

p007 / SI page 7 · Figure S10 discussion · Figure S10

SolventsNMP
AdditivesPVDF binder only; no CNT
Atmospherecoin cell testing atmosphere not separately restated for this control
Substrate orientationelectrode in Li half-cell
Work-upelectrode prepared without CNTs
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherCu-BHT active material87.5 wt%p007 / SI page 7 · Figure S10 discussion · Figure S10
AdditivePVDF12.5 wt%p007 / SI page 7 · Figure S10 discussion · Figure S10
Partial recipeSource: Both

Route 5: Other

p002-p004 / 12017-12019 · Materials Characterization and Stability Evaluation; Experimental Section · Figure 1a

Metal precursorsCu(II) salt; exact salt and stoichiometry not given in this paper
Linker precursorsbenzenehexathiolate precursor BHT
Solventsethanol
Additivesnone reported
AtmosphereAr
Temperatureroom temperature
Time12
Work-upnot specified for powder synthesis in this paper
Activationseparate dichloromethane solvent exchange and vacuum drying reported for characterisation
Scalability contextReported yield 43%, almost three times higher than interfacial-growing method.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCu(II) salts / Cu2+Not specifiedp002-p004 / 12017-12019 · Materials Characterization and Stability Evaluation; Experimental Section · Figure 1a
LinkerBHT / benzenehexathiolate precursorNot specifiedp002-p004 / 12017-12019 · Materials Characterization and Stability Evaluation; Experimental Section · Figure 1a
SolventethanolNot specifiedp002-p004 / 12017-12019 · Materials Characterization and Stability Evaluation; Experimental Section · Figure 1a