Measurement evidence
Reversible iodine absorption of nonporous coordination polymer Cu(TCNQ) · Miyao K., Funabiki A., Takahashi K. et al. · New Journal of Chemistry · 2014 · 739-743
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Cu(TCNQ)I4 from phase I by liquid-phase iodine absorption · Powder
phase I Cu(TCNQ) before liquid-phase iodine absorption, after absorption, and after annealing desorption
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| XRD crystallinity of liquid-phase Cu(TCNQ)I4 | product exhibited higher crystallinity than the solid-state reaction product | — | — | Text Qualitative | p003 / article page 741 · Results · Fig. 6 |
regenerated phase II Cu(TCNQ) after iodine desorption by annealing · Powder
repeated absorption-desorption experiments on phase I and phase II Cu(TCNQ)
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| phase conversion during repeated absorption-desorption | phase II Cu(TCNQ) gradually converted to phase I Cu(TCNQ) | — | — | Text Qualitative | p002 / article page 740 · Results · Fig. S1 |
Cu(TCNQ)I4 from phase II by solid-state grinding · Powder
phase II Cu(TCNQ) before iodine absorption, after solid-state iodine absorption, and after annealing desorption
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| XRD pattern after solid-state iodine absorption from phase II | almost same amorphous XRD pattern as phase I-derived Cu(TCNQ)I4, with several weak peaks | — | — | Text Qualitative | p001 / article page 739 · Results · Fig. 3 |
Cu(TCNQ)I4 from phase I by solid-state grinding · Powder
phase I Cu(TCNQ) before iodine absorption, after solid-state iodine absorption, and after annealing desorption
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| XRD pattern after solid-state iodine absorption from phase I | almost the same amorphous XRD patterns with several weak peaks | — | — | Text Qualitative | p001 / article page 739 · Results · Fig. 3 |
| phase I regeneration after annealing | regenerated corresponding phase of Cu(TCNQ); weaker XRD intensities and CuI peaks observed | — | — | Text Qualitative | p002 / article page 740 · Results · Fig. 3 |
Cu(TCNQ)I2 from phase I by stepwise solid-state iodine addition · Powder
Cu(TCNQ)In n = 1, 2, and 4 from stepwise solid-state reaction of phase I
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| CuI peak evolution in stepwise solid-state products | CuI peaks very evident for n = 1 and 2, barely evident for n = 4 | — | — | Text Qualitative | p003 / article page 741 · Results · Fig. 5; Fig. S3 |
| Cu(TCNQ) peak disappearance in stepwise solid-state phase I iodine addition | peaks of Cu(TCNQ) disappeared for Cu(TCNQ)In n = 1-2 | — | — | Text Qualitative | p002 / article page 740 · Results · Fig. 5 |
Cu(TCNQ)I2 from phase II by stepwise solid-state iodine addition · Powder
Cu(TCNQ)In n = 1, 2, 3, and 4 from stepwise solid-state reaction of phase II
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| phase II stepwise solid-state iodine series observed | Cu(TCNQ)In n = 1, 2, 3, and 4 XRD series with CuI peak markers | — | — | Caption Qualitative | p002 · Supporting Information · Fig. S3 |
Cu(TCNQ)In n = 2.1 liquid-phase short-reaction mixture · Powder
Cu(TCNQ)In n = 2.1 from short liquid-phase reaction of phase I Cu(TCNQ)
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| composition of short liquid-phase n = 2.1 product | 1:1 mixture of Cu(TCNQ) and Cu(TCNQ)I4 | — | — | Text Approximate | p003 / article page 741 · Results · Fig. S6 |
| TG weight-loss labels for liquid-phase n = 2.1 mixture | 40.1% and 50.2% labelled on Fig. S6 liquid-phase trace | — | figure labels are small and trace assignment is visual | Figure Axis Uncertain | p003 · Supporting Information · Fig. S6 |
homogeneous [CuI(TCNQ)](I2)0.5 after ball-milling liquid-phase n = 2.1 product · Powder
liquid-phase Cu(TCNQ)In n = 2.1 after ball-milling
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| homogeneous product after milling liquid-phase n = 2.1 sample | homogeneous [CuI(TCNQ)](I2)0.5 confirmed by XRD and TG | — | — | Text Qualitative | p003 / article page 741 · Results · Fig. S6 |
| TG weight-loss labels for milled n = 2.1 product | 27.1% and 50.3% labelled on Fig. S6 milled trace | — | figure labels are small and trace assignment is visual | Figure Axis Uncertain | p003 · Supporting Information · Fig. S6 |