Zhang M., Zhang A.-M., Wang X.-X. et al. · Journal of Materials Chemistry A · 2018 · 8735-8741
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
PMo10V2-ILs@MIL-100 delivers superior cycling stability and rate capability among reported MOF-, POM- and POMOF-based crystal anode materials.
Caveat: Comparative literature table S5 is not available locally, so the broad 'best amongst reported' claim cannot be independently checked from supplied documents.
5 (journal p. 8739) · Results and discussion · Table S5 referenced · Linked to 5 structured results
The authors note that synthesis of PMo10V2-ILs@MIL-100 is complex and ionic liquids are not cheap.
2 (journal p. 8736) · Introduction
IL diffusion into PMo10V2@MIL-100 does not break the POMOF/MIL-100 crystalline structure.
Caveat: Structural schemes are in SI Fig. S2; no CIF was supplied in the assigned documents.
3 (journal p. 8737) · Results and discussion · Fig. 1a,b · Linked to 3 structured results
PMo10V2-ILs@MIL-100 shows hybrid battery/supercapacitor lithium-storage behaviour, with capacitance and Li+ insertion/extraction both contributing.
Caveat: The b-value interpretation in the article appears reversed relative to common convention, but the extracted claim follows the authors' stated interpretation of mixed behaviour for b values between 0.5 and 1.
6 (journal p. 8740) · Results and discussion · Fig. 3 · Linked to 4 structured results
Larger MIL-100 mesoporous cages and higher surface area improve capacitive contribution relative to PMo10V2-ILs@HKUST-1.
Caveat: Numerical surface-area values are in SI Fig. S3 discussion, and cage-size comparisons are in SI Fig. S12; pore-size distributions are graphical.
6 (journal p. 8740) · Results and discussion · Fig. S3, S12, S15 referenced · Linked to 4 structured results
Encapsulated imidazolium ionic liquids improve ionic and electronic conductivity of PMo10V2@MIL-100, producing a much higher bulk conductivity and faster Li+ transport.
Caveat: Bulk-conductivity method is two-probe on pressed powders; detailed Table S1 and EIS fitting are in the SI.
5 (journal p. 8739) · Results and discussion · Table S1 and Fig. S13 referenced · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| ILs@MIL-100 | 1-ethyl-3-methylimidazolium-loaded Fe-BTC MIL-100Fe(III) clusters · BTC | 3D · CompositeMIL-100 framework loaded with ionic liquid but without PMo10V2. | 3 (journal p. 8737) · Results and discussion · Fig. S2 referenced |
| MIL-100(Fe) | Fe-BTC MIL-100trinuclear Fe(III) clusters · benzene-1,3,5-tricarboxylate (BTC) | 3D · PristineMIL-100 3D mesoporous framework; each trinuclear iron cluster is bridged by six BTC ligands. | 3 (journal p. 8737) · Results and discussion · Fig. S2a referenced |
| PMo10V2 | H5PMo10V2O40Keggin-type polyoxometalate containing Mo and V | 0D · PristineMolecular Keggin-type POM precursor/control. | 2 (journal p. 8736) · Experimental |
| PMo10V2@HKUST-1Browse family: HKUST-1 / Cu₃(BTC)₂ | PMo10V2 encapsulated in Cu-BTC HKUST-1Cu nodes with PMo10V2 guest · BTC | 3D · CompositePOMOF control based on HKUST-1 external framework. | 2 (journal p. 8736) · Experimental |
| PMo10V2-ILs@HKUST-1Browse family: HKUST-1 / Cu₃(BTC)₂ | {Cu2[C6H3(CO2)3]4/3}6[PMo10V2O40]0.9516[C6H11N2]4.875 (speculated from ICP/elemental analysis)Cu nodes with PMo10V2 and imidazolium IL guests · BTC | 3D · CompositeHKUST-1 analogue with the same internal PMo10V2-ILs material but different external structure. | 14 · Calculation of the theoretical capacities |
| PMo10V2-ILs@MIL-100 | {Fe3O(H2O)2OH[C6H3(CO2)3]2}[PMo10V2O40]0.2641[C6H11N2]1.213 (speculated from ICP/elemental analysis)Fe(III) clusters with PMo10V2 and 1-ethyl-3-methylimidazolium guests · BTC | 3D · CompositeIonic-liquid-functionalised POMOF; PMo10V2-ILs immobilised in MIL-100 cages. | 14 · Calculation of the theoretical capacities |
| PMo10V2@MIL-100 | H5PMo10V2O40 encapsulated in Fe-BTC MIL-100Fe(III) clusters with Keggin-type PMo10V2 guest · BTC | 3D · CompositePOMOF control: PMo10V2 is confined in the mesoporous cage of MIL-100. | 2 (journal p. 8736) · Experimental |
| PMo12-ILs@MIL-100 | PMo12-ILs@Fe-BTC MIL-100Fe(III) clusters with PMo12 and imidazolium IL guests · BTC | 3D · CompositeMIL-100 analogue of the target in which PMo10V2 is replaced by PMo12. | 3 (journal p. 8737) · Results and discussion · Fig. S2b referenced |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| ILs@MIL-100 composite electroderesearch_0368__mat__mat_ils_mil100 | Electrode · Pristine Control · Composite | active material/carbon black/PVDF = 7:2:1 pasted on Cu foilCu foil | 3 (journal p. 8737) · Electrochemical characterization |
| ILs@MIL-100 crystalsresearch_0368__mat__mat_ils_mil100 | Powder · Pristine Control · Guest Loaded | IL-loaded MIL-100 control prepared by analogue ion-exchange method | 2 (journal p. 8736) · Experimental |
| MIL-100 composite electroderesearch_0368__mat__mat_mil100_fe | Electrode · Pristine Control · Composite | active material/carbon black/PVDF = 7:2:1 pasted on Cu foilCu foil | 3 (journal p. 8737) · Electrochemical characterization |
| MIL-100(Fe) crystalsresearch_0368__mat__mat_mil100_fe | Powder · Pristine Control · Pristine Framework | hydrothermally prepared crystals | 2 (journal p. 8736) · Experimental |
| PMo10V2 composite electroderesearch_0368__mat__mat_pmo10v2 | Electrode · Pristine Control · Composite | active material/carbon black/PVDF = 7:2:1 pasted on Cu foilCu foil | 3 (journal p. 8737) · Electrochemical characterization |
| PMo10V2@HKUST-1 crystalsresearch_0368__mat__mat_pmo10v2_hkust1 | Powder · Pristine Control · Guest Loaded | solution precipitated PMo10V2-loaded HKUST-1 intermediate | 2 (journal p. 8736) · Experimental |
| PMo10V2-ILs@HKUST-1 composite electroderesearch_0368__mat__mat_pmo10v2_ils_hkust1 | Electrode · Pristine Control · Composite | active material/carbon black/PVDF = 7:2:1 pasted on Cu foilCu foil | 5 (journal p. 8739) · Results and discussion · Fig. S11 referenced |
| PMo10V2-ILs@HKUST-1 crystalsresearch_0368__mat__mat_pmo10v2_ils_hkust1 | Powder · Pristine Control · Guest Loaded | HKUST-1 analogue prepared by same IL exchange method | 2 (journal p. 8736) · Experimental |
| PMo10V2-ILs@MIL-100 composite electroderesearch_0368__mat__mat_pmo10v2_ils_mil100 | Electrode · Target Sample · Composite | active material/carbon black/PVDF = 7:2:1 pasted on Cu foil; active loading around 1 mgCu foil | 3 (journal p. 8737) · Electrochemical characterization |
| PMo10V2-ILs@MIL-100 crystalsresearch_0368__mat__mat_pmo10v2_ils_mil100 | Powder · Target Sample · Guest Loaded | ion-exchanged IL-loaded POMOF crystals; powder pellets pressed for conductivity | 2 (journal p. 8736) · Experimental |
| PMo10V2@MIL-100 composite electroderesearch_0368__mat__mat_pmo10v2_mil100 | Electrode · Pristine Control · Composite | active material/carbon black/PVDF = 7:2:1 pasted on Cu foilCu foil | 3 (journal p. 8737) · Electrochemical characterization |
| PMo10V2@MIL-100 crystalsresearch_0368__mat__mat_pmo10v2_mil100 | Powder · Pristine Control · Guest Loaded | hydrothermally prepared POMOF crystals | 2 (journal p. 8736) · Experimental |
| PMo10V2 control powderresearch_0368__mat__mat_pmo10v2 | Powder · Pristine Control · Pristine Framework | POM precursor/control | 2 (journal p. 8736) · Experimental |
| PMo12-ILs@MIL-100 crystalsresearch_0368__mat__mat_pmo12_ils_mil100 | Powder · Pristine Control · Guest Loaded | analogue IL-loaded PMo12 POMOF crystals | 3 (journal p. 8737) · Results and discussion · Fig. S2b referenced |