Synthesis · Encapsulating ionic liquids into POM-based MOFs to improve their conductivity for superior lithium storage

7 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

2 (journal p. 8736) · Materials and synthetic procedures

Metal precursorsMIL-100

SolventsH2O (25 mL inferred from same method)

Additivesexcess ILs

Temperatureroom temperature

Time24

Oxidant / reductantion-exchange analogue

Work-upcollected by centrifugation and washed with diethyl ether

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Additive	ILs	excess	2 (journal p. 8736) · Materials and synthetic procedures
Other	MIL-100	replaces PMo10V2@MIL-100; exact amount not stated	2 (journal p. 8736) · Materials and synthetic procedures
Solvent	H2O	25 mL inferred from same method	2 (journal p. 8736) · Materials and synthetic procedures

Partial recipeSource: Main

Route 2: Hydrothermal

2 (journal p. 8736) · Materials and synthetic procedures

Metal precursorsFeCl3.6H2O (1.62 g)

Linker precursorsbenzene-1,3,5-tricarboxylic acid (BTC, 0.834 g)

SolventsH2O (30 mL)

Temperature130

Time72

Work-upfiltered and washed with acetone

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	FeCl3.6H2O	1.62 g	2 (journal p. 8736) · Materials and synthetic procedures
Linker	BTC	0.834 g	2 (journal p. 8736) · Materials and synthetic procedures
Solvent	H2O	30 mL	2 (journal p. 8736) · Materials and synthetic procedures

Partial recipeSource: Main

Route 3: Other

2 (journal p. 8736) · Materials and synthetic procedures

Metal precursorsCu(OAc)2.H2O (0.2 g); PMo10V2 (0.22 g)

Linker precursorsBTC (0.14 g)

SolventsH2O (10 mL) for Cu/POM solution; alcohol (10 mL) for BTC solution

AdditivesPMo10V2 polyoxometalate guest

Temperatureroom temperature

Work-upBTC solution added dropwise under continuous stirring; precipitate collected by centrifugation and washed with alcohol and deionized water

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(OAc)2.H2O	0.2 g	2 (journal p. 8736) · Materials and synthetic procedures
Additive	PMo10V2	0.22 g	2 (journal p. 8736) · Materials and synthetic procedures
Linker	BTC	0.14 g	2 (journal p. 8736) · Materials and synthetic procedures
Solvent	H2O	10 mL	2 (journal p. 8736) · Materials and synthetic procedures
Solvent	alcohol	10 mL	2 (journal p. 8736) · Materials and synthetic procedures

Partial recipeSource: Main

Route 4: Other

2 (journal p. 8736) · Materials and synthetic procedures

Metal precursorsPMo10V2@HKUST-1

SolventsH2O (25 mL inferred from same method)

Additivesexcess ILs

Temperatureroom temperature

Time24

Oxidant / reductantion-exchange analogue

Work-upcollected by centrifugation and washed with diethyl ether

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Additive	ILs	excess	2 (journal p. 8736) · Materials and synthetic procedures
Other	PMo10V2@HKUST-1	replaces PMo10V2@MIL-100; exact amount not stated	2 (journal p. 8736) · Materials and synthetic procedures

Partial recipeSource: Main

Route 5: Other

2 (journal p. 8736) · Materials and synthetic procedures

Metal precursorsPMo10V2@MIL-100 (2.0 g)

SolventsH2O (25 mL)

Additivesexcess 1-ethyl-3-methylimidazolium bromide (ILs)

Temperatureroom temperature

Time24

Oxidant / reductantanion-exchange / ion-exchange procedure

Work-upcollected by centrifugation and washed with diethyl ether

Scalability contextAuthors note the synthesis is complex and ionic liquids are not cheap.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Additive	ILs (1-ethyl-3-methylimidazolium bromide)	excess	2 (journal p. 8736) · Materials and synthetic procedures
Other	PMo10V2@MIL-100	2.0 g	2 (journal p. 8736) · Materials and synthetic procedures
Solvent	H2O	25 mL	2 (journal p. 8736) · Materials and synthetic procedures

Partial recipeSource: Main

Route 6: Hydrothermal

2 (journal p. 8736) · Materials and synthetic procedures

Metal precursorsFeCl3.6H2O (0.945 g); PMo10V2 (2.036 g)

Linker precursorsBTC (0.68 g)

SolventsH2O (25 mL)

AdditivesPMo10V2 polyoxometalate guest

Temperature130

Time72

Work-upfiltered and washed with ethanol and ether

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	FeCl3.6H2O	0.945 g	2 (journal p. 8736) · Materials and synthetic procedures
Linker	BTC	0.68 g	2 (journal p. 8736) · Materials and synthetic procedures
Additive	PMo10V2	2.036 g	2 (journal p. 8736) · Materials and synthetic procedures
Solvent	H2O	25 mL	2 (journal p. 8736) · Materials and synthetic procedures

Partial recipeSource: Main

Route 7: Other

2 (journal p. 8736) · Materials and synthetic procedures

Metal precursorsPMo12@MIL-100

SolventsH2O (25 mL inferred from same method)

Additivesexcess ILs

Temperatureroom temperature

Time24

Oxidant / reductantion-exchange analogue

Work-upcollected by centrifugation and washed with diethyl ether

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Additive	ILs	excess	2 (journal p. 8736) · Materials and synthetic procedures
Other	PMo12@MIL-100	replaces PMo10V2@MIL-100; exact amount not stated	2 (journal p. 8736) · Materials and synthetic procedures