Xie Y., Wang X., Yan Z. et al. · Talanta · 2025 · 127196
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The final ECL biosensor detects ATP linearly from 5 to 1000 nM with an LOD of 1.18 nM and good serum recovery.
Caveat: Sensing performance is application context rather than intrinsic MOF electrical transport.
7 · 3.5-3.6 · Fig. 5; Tables 1-2 · Linked to 5 structured results
SI Table S1 positions this work among reported ATP analytical methods, with the ECL biosensor giving a 5e-9 to 1e-6 M linear range and 1.18e-9 M LOD.
Caveat: Most Table S1 rows are literature comparisons, not first-hand measurements from this paper.
S10 · Table S1 · Table S1 · Linked to 1 structured result
The article discusses large/specific surface area qualitatively but the assigned main text and SI do not report BET surface area or pore-size values for these materials.
Caveat: Porosity may exist in raw supplemental figures/data not included in the text-only SI, but no numeric porosity data were present in the assigned documents.
3 · 3.2
BDC is assigned as a morphologic regulator that improves framework stability and supports ultrathin nanosheet formation.
Caveat: Framework stability is asserted qualitatively; no stability metric for isolated BDC role was reported.
2 · Introduction · Scheme 1A · Linked to 2 structured results
Ru(bpy)3(2+) loading does not significantly change the Zn mMOFs-NH2 framework structure, which remains MOF-5-like by XRD.
Caveat: No CIF/refinement was provided in the assigned files.
3 · 3.1 · Fig. 1B · Linked to 4 structured results
The mixed-ligand strategy produces ultrathin 2D lamellar morphology and smaller EIS semicircles, which the authors interpret as enhanced electrical conductivity/electron transfer.
Caveat: Conductivity is inferred from EIS semicircle trends; no direct bulk conductivity value was reported.
3 · 3.2 · Fig. 2G · Linked to 2 structured results
NH2-BDC acts as a co-reaction accelerator by promoting S2O8(2-) reduction to SO4 radical species around Ru(bpy)3(2+), strengthening self-enhanced ECL.
Caveat: Mechanistic claim is supported by ECL/EIS trends and proposed reactions rather than direct radical quantification in the extracted text.
4 · 3.2 · Fig. 3 · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Ru(bpy)3(2+)@Zn mMOFs-NH2-CP/ATP/AP/AuNPs/GCE biosensor electrode | GCE/AuNPs/AP/ATP/Ru(bpy)3(2+)@Zn mMOFs-NH2-CPZn2+ framework nodes; AuNP film; Ru(bpy)3(2+) guest · BDC; NH2-BDC; DNA aptamer/capture probe | unknown · CompositeLayered electrochemical biosensor assembly on glassy carbon electrode | 6 · 3.3 · Fig. 4 caption |
| Bare glassy carbon electrode | GCE | unknown · Model SystemNon-MOF electrochemical control electrode | 4 · 3.3 · Fig. 4 caption |
| Ru(bpy)3(2+)@Zn mMOFs-NH2-CP | capture-probe functionalised Ru(bpy)3(2+)@Zn mMOFs-NH2Zn2+ framework nodes; Ru(bpy)3(2+) guest · BDC; NH2-BDC; amide-linked DNA capture probe | 3D · CompositeFunctionalised nanoreactor probe formed by amide coupling to NH2 groups | 2 · Introduction · Scheme 1B |
| Ru(bpy)3(2+)@Zn mMOFs-NH2 | Ru(bpy)3(2+) encapsulated in Zn(BDC/NH2-BDC) mMOFZn2+ framework nodes; Ru(bpy)3(2+) guest luminophore · BDC; NH2-BDC | 3D · CompositeMOF-5-like Zn framework retained after Ru(bpy)3(2+) loading; XRD peaks at 6.8, 9.6, 13.7 and 15.5 degrees assigned to (200), (220), (400), (420) | 2 · Introduction · Scheme 1A |
| Ru(bpy)3(2+)@Zn MOFs | Ru(bpy)3(2+) encapsulated in BDC-only Zn MOFZn2+ framework nodes; Ru(bpy)3(2+) guest · BDC only | unknown · CompositeBDC-only control described as quadrilateral lamellar morphology | 3 · 3.2 · Fig. 2A,D |
| Ru(bpy)3(2+)@Zn MOFs-NH2 | Ru(bpy)3(2+) encapsulated in NH2-BDC-only Zn MOFZn2+ framework nodes; Ru(bpy)3(2+) guest · NH2-BDC only | unknown · CompositeNH2-BDC-only control described as irregular blocky morphology | 3 · 3.2 · Fig. 2B,E |
| Zn mMOFs-NH2 | Zn MOF from BDC and NH2-BDC ligandsZn2+ from zinc acetate dihydrate · 1,4-benzenedicarboxylic acid (BDC); 2-aminoterephthalic acid (NH2-BDC) | 3D · PristineMOF-5-like XRD pattern; ultrathin lamellar nanosheet morphology when prepared with mixed ligands | 3 · 3.1 · Fig. 1B |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| AP/AuNPs/GCEresearch_0377__mat__mat_biosensor_electrode | Electrode · Composite Sample · Composite | ATP aptamer probe immobilised by Au-S affinityAuNPs/GCE | 3 · 2.2 · Scheme 1C |
| ATP/AP/AuNPs/GCEresearch_0377__mat__mat_biosensor_electrode | Electrode · Composite Sample · Composite | AP/AuNPs/GCE after ATP incubationAP/AuNPs/GCE | 3 · 2.2 · Scheme 1C |
| AuNPs/GCEresearch_0377__mat__mat_biosensor_electrode | Electrode · Composite Sample · Composite | AuNP membrane electrodeposited on GCEglassy carbon electrode | 3 · 2.2 · Fig. S1 |
| Bare GCEresearch_0377__mat__mat_gce_electrode | Electrode · Model System · Model | polished and cleaned bare electrodeglassy carbon electrode | 3 · 2.2 |
| Ru(bpy)3(2+)@Zn mMOFs-NH2-CP/ATP/AP/AuNPs/GCEresearch_0377__mat__mat_biosensor_electrode | Electrode · Composite Sample · Composite | final ECL ATP biosensor after MOF-CP captureGCE/AuNPs/AP/ATP | 3 · 2.2 · Scheme 1C |
| Ru(bpy)3(2+)@Zn mMOFs-NH2-CP nanoproberesearch_0377__mat__mat_ru_probe | Powder · Composite Sample · Composite | EDC/NHS coupled DNA capture probe on Ru-loaded MOF | 3 · 2.2 · Scheme 1B |
| Ru(bpy)3(2+)@Zn mMOFs-NH2research_0377__mat__mat_ru_zn_mmofs_nh2 | Nanosheet · Target Sample · Guest Loaded | powder nanoreactor after centrifugation and washing | 3 · 2.1 |
| Ru(bpy)3(2+)@Zn MOFsresearch_0377__mat__mat_ru_zn_mofs_bdc | Nanosheet · Pristine Control · Guest Loaded | BDC-only Ru-loaded Zn MOF control | 3 · 2.1 |
| Ru(bpy)3(2+)@Zn MOFs-NH2research_0377__mat__mat_ru_zn_mofs_nh2 | Powder · Pristine Control · Guest Loaded | NH2-BDC-only Ru-loaded Zn MOF control | 3 · 2.1 |
| Zn mMOFs-NH2research_0377__mat__mat_zn_mmofs_nh2 | Nanosheet · Pristine Control · Pristine Framework | mixed-ligand Zn MOF host, no Ru(bpy)3(2+) | 3 · 2.1 |