Electrical Transport — A conducting coordination polymer based on assembled Cu9 cages

Measurement evidence

Electrical Transport

A conducting coordination polymer based on assembled Cu9 cages · Delgado S., Sanz Miguel P.J., Priego J.L. et al. · Inorganic Chemistry · 2008 · 9128-9130

2 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Four-contact dc electrical conductivity with Arrhenius analysis

compound 1 conductivity crystal, higher-conductivity specimen · Single Crystal

Single crystal measured in a Quantum Design PPMS-9 with dc currents between 5 and 100 nA; Pt wire contacts along the long needle axis. Figure 2 plots sigma versus T and inset ln sigma versus 1000/T.

Temperature
room temperature; figure axis approximately 258-300 K
Geometry
Four contact; Pt wires along long axis; graphite paste contacts
Context
pristine framework
Measurement source
main p.3, article p.9130 · main text · Figure 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy, higher crystalMarked as a best value within this paper110 meVText
Rounded Reported
main p.3, article p.9130 · main text · Figure 2
room-temperature conductivity, higher crystalMarked as a best value within this paper1.6 x 10-3 S.cm-1 at room temperatureText
Rounded Reported
main p.3, article p.9130 · main text · Figure 2
conductivity from Figure 2 near 258 Kapproximately 8.6 x 10-4 S cm-1 at ca. 258 Kvisual estimateFigure Axis
Approximate
main p.3, article p.9130 · Figure 2 · Figure 2
conductivity from Figure 2 near 280 Kapproximately 1.15 x 10-3 S cm-1 at ca. 280 Kvisual estimateFigure Axis
Approximate
main p.3, article p.9130 · Figure 2 · Figure 2
conductivity from Figure 2 near 290 Kapproximately 1.38 x 10-3 S cm-1 at ca. 290 Kvisual estimateFigure Axis
Approximate
main p.3, article p.9130 · Figure 2 · Figure 2

Four-contact dc electrical conductivity

compound 1 conductivity crystal, lower-conductivity specimen · Single Crystal

Single crystal measured in a Quantum Design PPMS-9 with dc currents between 5 and 100 nA; Pt wires (25 um diameter) along the needle long axis using graphite paste; cooling/warming rate 0.1 K min-1.

Temperature
room temperature; variable temperature
Geometry
Four contact; Pt wires along long axis; graphite paste contacts
Context
pristine framework
Measurement source
SI p.S-10 · Conductivity Measurements
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy, lower crystal109 meVText
Rounded Reported
SI p.S-10 · Conductivity Measurements
room-temperature conductivity, lower crystal1.0x10-3 S.cm-1 at room temperatureText
Rounded Reported
SI p.S-10 · Conductivity Measurements