cMOF Evidence Base
Other — A conducting coordination polymer based on assembled Cu9 cages

Measurement evidence

Other

A conducting coordination polymer based on assembled Cu9 cages · Delgado S., Sanz Miguel P.J., Priego J.L. et al. · Inorganic Chemistry · 2008 · 9128-9130

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Variable-temperature magnetic susceptibility by Quantum Design MPMS-XL SQUID

Magnetometry and magnetic susceptibility

compound 1 polycrystalline magnetic sample · Powder

Polycrystalline sample measured from 2 to 300 K under an applied magnetic field of 1 T; diamagnetic corrections applied.

Temperature
2-300
Context
pristine framework
Measurement source
main p.3, article p.9130 · main text
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
compound 1 magnetic behaviourdiamagnetic from 2-300 K——Text
Qualitative		main p.3, article p.9130 · main text

Variable-temperature magnetic susceptibility fitted to Bleaney-Bowers S = 1/2 dimer model

Magnetometry and magnetic susceptibility

compound 2 crystals · Single Crystal

Magnetic behaviour of compound 2 measured from 2 to 300 K and fitted to obtain weak antiferromagnetic coupling.

Temperature
2-300
Context
molecular co-product
Measurement source
main p.3, article p.9130 · main text · Figure SI-2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
compound 2 magnetic moment at 2 Kca. 2.69 muB at 2 K—ca.Text
Approximate		main p.3, article p.9130 · main text · Figure SI-2
compound 2 fitted g valueg = 2.25—read from figure labelVisual Estimate
Rounded Reported		SI p.S-4 · Figure SI-2 · Figure SI-2
compound 2 room-temperature magnetic moment2.77 muB per CuII dimer——Text
Exact Reported		main p.3, article p.9130 · main text · Figure SI-2
compound 2 weak antiferromagnetic coupling parameter zJ-0.12 cm-1——Text
Rounded Reported		main p.3, article p.9130 · main text · Figure SI-2