Ding H., Liu P., Liu C. et al. · ChemSusChem · 2025 · e202401606
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The paper motivates C-MOFs by high electrical conductivity and reports EIS/DFT proxies, but it does not provide a direct intrinsic electrical-transport measurement for pristine 2D Cu-TABQ.
Caveat: Absence determined from the provided main and SI text/images.
main p.1 · Abstract/Introduction · Linked to 2 structured results
PVA/Zn(CF3SO3)2 hydrogel electrolyte with lower water content reduces TABQ linker dissolution and improves flexible-cell cycling stability.
Caveat: Dissolution evidence is mainly visual and electrochemical rather than quantified chemical analysis of electrolyte.
main p.7 · Flexible Batteries · Figure S18 · Linked to 4 structured results
XRD positions, FT-IR/Raman coordination features, XPS and EDS mapping support successful synthesis of 1D Cu-TABQ and 2D Cu-TABQ C-MOFs.
Caveat: No CIF or full crystallographic refinement was provided in the assigned documents.
main p.2 · Structural Characterization · Figure 1c-e · Linked to 4 structured results
The 2D coordination configuration, higher surface area and lower charge-transfer resistance are proposed to explain the better rate and cycling performance of 2D Cu-TABQ relative to 1D Cu-TABQ.
Caveat: Specific surface area is only reported qualitatively; direct intrinsic electrical conductivity was not measured.
main p.4 · Electrochemical Performance · Figure 3, Figure S9 · Linked to 6 structured results
The high-frequency C=O shift in 2D Cu-TABQ is interpreted as evidence that carbonyl groups do not coordinate to Cu; N atoms coordinate to Cu2+.
Caveat: Assignment is spectroscopic and literature-supported; no direct local structural refinement was reported.
main p.2 · Structural Characterization · Figure 1d-e · Linked to 3 structured results
DFT gives lower LUMO and smaller HOMO-LUMO gap for 2D Cu-TABQ than 1D Cu-TABQ, which the authors link to stronger electron affinity and better electrical conductivity.
Caveat: Electrical conductivity is inferred from calculated gap; no direct conductivity measurement is reported.
main p.6 · Storage Mechanism · Figure 5a · Linked to 4 structured results
2D Cu-TABQ stores Zn2+ through triple redox-active centres: C=O/C-O, C=N/C-N and Cu2+/Cu+.
Caveat: Mechanistic assignment is based on ex-situ spectra and DFT ESP, not operando structure determination.
main p.5 · Storage Mechanism · Figure 4 · Linked to 7 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| 1D Cu-TABQ | Cu-TABQ framework; exact empirical formula not reportedCu ions coordinated to deprotonated TABQ amine nitrogens · 2,3,5,6-tetraaminobenzoquinone (TABQ) | 1D · PristineOne-dimensional Cu-TABQ coordination polymer prepared in ammonia; used as the pristine lower-dimensional control. | main p.2 · Structural Characterization · Figure 1b |
| 2D Cu-TABQ | Cu-TABQ framework; exact empirical formula not reportedCu ions, with Cu+ and Cu2+ observed by Cu 2p XPS · 2,3,5,6-tetraaminobenzoquinone (TABQ) | 2D · PristineTwo-dimensional pi-d conjugated conductive metal-organic framework; N coordinates to Cu2+ and carbonyl groups are not assigned as Cu-coordination sites. | main p.1 · Abstract |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| 1D Cu-TABQ composite cathode in CR2032 Zn cellresearch_0398__mat__cu_tabq_1d | Electrode · Composite Sample · Composite | 1D Cu-TABQ powder/Ketjen Black/PTFE 6:3:1 in NMP, coated on stainless steel, dried at 80 C for 12 h and cut to 10 mm disks.Stainless steel current collector; Zn foil counter/anode in CR2032 coin cell. | main p.7 · ZIBs Fabrication |
| DFT model of 1D Cu-TABQresearch_0398__mat__cu_tabq_1d | Model · Model System · Model | Gaussian 16 A.03/PBE0-D3(BJ)/def2-SVP geometry optimisation and frequency calculation.not_applicable | main p.8 · Computational Method · Figure 5 and Figure S13 |
| Pristine 1D Cu-TABQ powderresearch_0398__mat__cu_tabq_1d | Powder · Pristine Control · Pristine Framework | Washed with ethanol and water and dried at 80 C for 12 h after room-temperature coordination polymerisation. | main p.7 · Materials Synthesis |
| 2D Cu-TABQ composite cathode in CR2032 Zn cellresearch_0398__mat__cu_tabq_2d | Electrode · Composite Sample · Composite | 2D Cu-TABQ powder/Ketjen Black/PTFE 6:3:1 in NMP, coated on stainless steel, dried at 80 C for 12 h and cut to 10 mm disks.Stainless steel current collector; Zn foil counter/anode in CR2032 coin cell. | main p.7 · ZIBs Fabrication |
| DFT model of 2D Cu-TABQresearch_0398__mat__cu_tabq_2d | Model · Model System · Model | Gaussian 16 A.03/PBE0-D3(BJ)/def2-SVP geometry optimisation and frequency calculation.not_applicable | main p.8 · Computational Method · Figure 5 |
| Flexible 2D Cu-TABQ//Zn cell with PVA/Zn(CF3SO3)2 hydrogel electrolyteresearch_0398__mat__cu_tabq_2d | Electrode · Composite Sample · Composite | Flexible sandwich cell assembled with 2D Cu-TABQ cathode, GF/C separator, Zn foil and PVA/Zn(CF3SO3)2 hydrogel electrolyte.Flexible cell stack; Zn foil anode and GF/C separator. · 2 x 3 cm2 cathode and 2 x 3 cm2 Zn foil anode. | main p.8 · ZIBs Fabrication · Figures S14-S15 |
| Pristine 2D Cu-TABQ powderresearch_0398__mat__cu_tabq_2d | Powder · Target Sample · Pristine Framework | Washed with ethanol and water and dried at 80 C for 12 h after solvothermal synthesis. | main p.7 · Materials Synthesis |