cMOF Evidence Base

Synthesis evidence

Two-Dimensional π-d Conjugated Conductive Metal-Organic Framework with Triple Active Centers as High-Performance Cathodes for Flexible Zinc Batteries

Ding H., Liu P., Liu C. et al. · ChemSusChem · 2025 · e202401606

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Other

main p.7 · ZIBs Fabrication

SolventsN-methyl pyrrolidone (NMP)
AdditivesKetjen Black and polytetrafluoroethylene binder
Atmospherenot specified
Temperature80
Time12 h drying
Substrate orientationCoated on stainless steel and cut into 10 mm circular electrode disks.
Work-upUniform coating, drying, disk cutting; assembled with Zn foil, 2M Zn(CF3SO3)2 and GF/C separator.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Other1D Cu-TABQ powder6 parts by weightmain p.7 · ZIBs Fabrication
AdditiveKetjen Black3 parts by weightmain p.7 · ZIBs Fabrication
Additivepolytetrafluoroethylene1 part by weightmain p.7 · ZIBs Fabrication
ElectrolyteZn(CF3SO3)22 Mmain p.7 · ZIBs Fabrication
Complete recipeSource: Main

Route 2: Other

main p.7 · Materials Synthesis

Metal precursorsCu(NO3)2.3H2O, 80.5 mg
Linker precursors2,3,5,6-tetraaminobenzoquinone (TABQ), 56 mg
SolventsDMSO, 10 mL for Cu solution plus 10 mL for TABQ solution
Additives1 mL concentrated aqueous ammonium hydroxide
Atmosphereair/not specified
Temperatureroom temperature reaction; dried at 80 C
Time12 h reaction; 12 h drying
Work-upProducts washed sequentially with ethanol and water.
ActivationDried at 80 C for 12 h.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCu(NO3)2.3H2O80.5 mgmain p.7 · Materials Synthesis
Linker2,3,5,6-tetraaminobenzoquinone (TABQ)56 mgmain p.7 · Materials Synthesis
SolventDMSO10 mL + 10 mLmain p.7 · Materials Synthesis
Baseconcentrated aqueous ammonium hydroxide1 mL · concentratedmain p.7 · Materials Synthesis
Complete recipeSource: Main

Route 3: Solvothermal

main p.7 · Materials Synthesis

Metal precursorsCu(NO3)2.3H2O, 108.7 mg, 0.45 mmol
Linker precursors2,3,5,6-tetraaminobenzoquinone (TABQ), 50.4 mg, 0.3 mmol
SolventsDMSO, 12 mL for TABQ plus 6 mL for Cu salt
Atmosphereair/not specified
Temperature120
Time12 h after 10 min sonication; 12 h drying
Work-upProducts washed sequentially with ethanol and water.
ActivationDried at 80 C for 12 h.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCu(NO3)2.3H2O108.7 mg, 0.45 mmolmain p.7 · Materials Synthesis
Linker2,3,5,6-tetraaminobenzoquinone (TABQ)0.3 mmol, 50.4 mgmain p.7 · Materials Synthesis
SolventDMSO12 mL + 6 mLmain p.7 · Materials Synthesis
Complete recipeSource: Main

Route 4: Other

main p.7 · ZIBs Fabrication

SolventsN-methyl pyrrolidone (NMP)
AdditivesKetjen Black and polytetrafluoroethylene binder
Atmospherenot specified
Temperature80
Time12 h drying
Substrate orientationCoated on stainless steel and cut into 10 mm circular electrode disks.
Work-upUniform coating, drying, disk cutting; assembled with Zn foil, 2M Zn(CF3SO3)2 and GF/C separator.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Other2D Cu-TABQ powder6 parts by weightmain p.7 · ZIBs Fabrication
AdditiveKetjen Black3 parts by weightmain p.7 · ZIBs Fabrication
Additivepolytetrafluoroethylene1 part by weightmain p.7 · ZIBs Fabrication
SolventN-methyl pyrrolidoneNot specifiedmain p.7 · ZIBs Fabrication
ElectrolyteZn(CF3SO3)22 Mmain p.7 · ZIBs Fabrication
Complete recipeSource: Main

Route 5: Other

main pp.7-8 · ZIBs Fabrication · Figures S14-S15

SolventsDeionised water, 10 mL
AdditivesPolyvinyl alcohol (PVA), 1.5 g; Zn(CF3SO3)2, 7.27 g
Atmospherenot specified
Temperature90
Time0.667 h stirring (40 min)
Substrate orientationFlexible sandwich cell: Zn foil 2 x 3 cm2, GF/C separator 2 x 3 cm2, 2D Cu-TABQ cathode 2 x 3 cm2.
Work-upHydrogel electrolyte prepared by stirring PVA and Zn(CF3SO3)2 in water; flexible cell assembled with hydrogel electrolyte.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
AdditivePolyvinyl alcohol (PVA)1.5 gmain pp.7-8 · ZIBs Fabrication · Figures S14-S15
ElectrolyteZn(CF3SO3)27.27 gmain pp.7-8 · ZIBs Fabrication · Figures S14-S15
Solventdeionized water10 mLmain pp.7-8 · ZIBs Fabrication · Figures S14-S15