Synthesis · Manipulating Photoconduction in Cu-Pyrene 1-D Coordination Nanosheets by Modulating Interlayer π-π Stacking

2 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

S5 · Scheme 2. Synthesis of Cu-PTT nanosheet · Scheme 2

Metal precursorsCuCl2.2H2O (16.29 mg, 0.12 mmol)

Linker precursorsPTT, 20 mg, 0.061 mmol

SolventsDMF for ligand precursor solution; degassed methanol for CuCl2.2H2O solution

AtmosphereDegassed solution; atmosphere not otherwise specified for nanosheet assembly

Temperatureroom temperature

Time0.5

Work-upBrown precipitate washed by centrifugation and oven dried for further characterisation

ActivationOven dried; no separate activation reported

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	CuCl2.2H2O	16.29 mg, 0.12 mmol	S5 · Scheme 2. Synthesis of Cu-PTT nanosheet · Scheme 2
Linker	PTT	20 mg, 0.061 mmol	S5 · Scheme 2. Synthesis of Cu-PTT nanosheet · Scheme 2
Solvent	DMF	Not specified	S5 · Scheme 2. Synthesis of Cu-PTT nanosheet · Scheme 2
Solvent	degassed methanol	Not specified	S5 · Scheme 2. Synthesis of Cu-PTT nanosheet · Scheme 2

Complete recipeSource: Both

S6 · Scheme 3. Synthesis of Cu-tBuPTT nanosheet · Scheme 3

Metal precursorsCuCl2.2H2O (20.41 mg, 0.12 mmol)

Linker precursorstBuPTT, 27 mg, 0.061 mmol