Sun L., Guo H., Liu B. et al. · Microchimica Acta · 2023 · 346
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The final composite sensor provides sensitive LEV detection across 0.05-600 uM with a 0.00610 uM LOD and acceptable recoveries in human serum and urine.
Caveat: Real-sample evidence includes main Table 2 and low-dilution SI Table S1; all are standard-addition spike recoveries.
p001 · Abstract · Linked to 6 structured results
The office SI text is incomplete at Table S1, but the rendered SI surrogate provides the figures, chronocoulometry/electroactive-area details, robustness values, and low-dilution Table S1 rows.
Caveat: Use rendered SI provenance for SI-only figure/table values; the office text alone would be incomplete.
p010 · S7. Real sample analysis · Table S1 · Linked to 3 structured results
The final TABQ-CHHO-COF/Poly-L-Cys/Tri-AgNP composite combines COF conductivity/porosity with poly-L-cysteine/Tri-AgNP active sites to accelerate electron transfer and improve LEV response.
Caveat: Evidence is electrochemical rather than direct microscopic proof of all interfacial interactions.
p008 · Conclusions · Linked to 3 structured results
FT-IR, PXRD, and XPS data support successful synthesis of TABQ-CHHO-COF by condensation of CHHO and TABQ.
Caveat: XPS figure itself is in the SI; main text reports the assignments and rendered SI verifies the figure/caption.
p004 · Physical characterizations of the modified materials · Fig. 1; Fig. S2 · Linked to 5 structured results
The pristine semiconducting TABQ-CHHO-COF improves electrode conductivity and lowers charge-transfer resistance relative to bare GCE.
Caveat: Conductivity measurement geometry is not given.
p005 · Electrochemical characterization of the modified electrodes · Fig. 2 · Linked to 3 structured results
LEV oxidation on the final composite electrode is an irreversible, adsorption-controlled process involving approximately two electrons and two protons.
Caveat: Mechanistic assignment is inferred from electrochemical regressions and Laviron analysis.
p006-p007 · Optimization of the experiment conditions · Scheme 2; Fig. S5 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| glassy carbon electrode | C | unknown · Model SystemCommercial glassy carbon working electrode, 3 mm diameter. | p003 · Apparatus and instruments |
| Poly-L-Cys/Tri-AgNP | Not specifiedTriangular Ag nanoplates · electropolymerised L-cysteine film | unknown · CompositeTriangular Ag nanoplates confined within porous poly-L-cysteine cavities through thiol-involved ligand exchange. | p002 · Introduction |
| TABQ-CHHO-COF | Not specifiednone · cyclohexanehexaone/cyclohexanehexone (CHHO) and tetraminophenone/tetraaminobenzoquinone (TABQ) condensation units | 2D · PristineNitrogen-rich semiconducting covalent organic framework with benzoquinone and triquinoxalinylene units, carbonyl and pyrazine groups, and PXRD peaks assigned to (220), (201), and (002) planes. | p002 · Introduction |
| TABQ-CHHO-COF/Poly-L-Cys/Tri-AgNP | Not specifiedTriangular Ag nanoplates as nanoparticle component; no framework metal nodes · TABQ-CHHO-COF plus electropolymerised L-cysteine | 2D · CompositeTernary nanocomposite combining semiconducting TABQ-CHHO-COF, poly-L-cysteine, and triangular Ag nanoplates for GCE modification. | p002 · Introduction |
| triangular Ag nanoplates | AgAg nanoplates | 0D · PristineShape-controlled triangular silver nanoplates used as a redox mediator and electroactive component. | p002 · Introduction |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| bare GCEresearch_0406__mat__mat_gce | Electrode · Pristine Control · Model | Polished with alumina powder, washed with ethanol and double-distilled water, and dried with nitrogen gas.glassy carbon electrode | p004 · Fabrication of TABQ-CHHO-COF/Poly-L-Cys/Tri-AgNP/GCE |
| TABQ-CHHO-COF/Poly-L-Cys/Tri-AgNP/GCEresearch_0406__mat__mat_tabq_chho_cof_poly_l_cys_tri_agnp | Electrode · Target Sample · Composite | TABQ-CHHO-COF/GCE coated with electropolymerised poly-L-cysteine, then 4 uL Tri-AgNP suspension drop-cast, incubated, and dried at room temperature.glassy carbon electrode | p004 · Fabrication of TABQ-CHHO-COF/Poly-L-Cys/Tri-AgNP/GCE |
| Poly-L-Cys/Tri-AgNP/GCEresearch_0406__mat__mat_poly_l_cys_tri_agnp | Electrode · Pristine Control · Composite | Control electrode containing poly-L-cysteine and triangular Ag nanoplates on GCE; detailed separate preparation not given in the main text.glassy carbon electrode | p004 · Electrochemical characterization of the modified electrodes · Fig. 2 |
| TABQ-CHHO-COF/GCEresearch_0406__mat__mat_tabq_chho_cof | Electrode · Pristine Control · Pristine Framework | 5 uL TABQ-CHHO-COF suspension drop-cast on pretreated GCE and dried under an infrared lamp.glassy carbon electrode | p004 · Fabrication of TABQ-CHHO-COF/Poly-L-Cys/Tri-AgNP/GCE |
| TABQ-CHHO-COF/Poly-L-Cys/GCE intermediateresearch_0406__mat__mat_tabq_chho_cof_poly_l_cys_tri_agnp | Electrode · Composite Sample · Composite | Cysteine electropolymerised on TABQ-CHHO-COF/GCE from 0.02 M cysteine at pH 1.0 over 25 cycles.glassy carbon electrode | p004 · Fabrication of TABQ-CHHO-COF/Poly-L-Cys/Tri-AgNP/GCE |
| TABQ-CHHO-COF powderresearch_0406__mat__mat_tabq_chho_cof | Powder · Composite Component · Pristine Framework | Black powder rinsed with water, methanol, and acetone, Soxhlet washed with methanol/water for 24 h, and annealed at 200 C for 5 h under nitrogen. | p003-p004 · Synthesis of TABQ-CHHO-COF |
| Tri-AgNP suspensionresearch_0406__mat__mat_tri_agnp | Unknown · Composite Component · Unknown | Ink-blue triangular Ag nanoplate suspension obtained after repeated centrifugation. | p004 · Synthesis of Tri-AgNP |