Electrochemistry Application — Modulating the electrical conductivity of metal-organic framework films with intercalated guest π-systems

6 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

BMOF/ZnO-FTO electrochemical film · Electrode

BMOF/ZnO-FTO working electrode; Pt mesh counter; Ag/AgCl reference; 0.1 M Bu4NPF6 supporting electrolyte.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BMOF oxidation potential	E1Ox = 920 mV vs Ag/AgCl	—	—	Figure Axis Exact Reported	S9 · Fig. S5 · Fig. S5
BMOF reduction potential	E1Red = -850 mV vs Ag/AgCl	—	—	Figure Axis Exact Reported	S9 · Fig. S5 · Fig. S5

BPDPNDI ligand solution · Model

1 mM BPDPNDI in 0.1 M Bu4NPF6/MeCN.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BPDPNDI oxidation potential	E1Ox = +880 mV vs Ag/AgCl	—	—	Figure Axis Exact Reported	S9 · Fig. S5 · Fig. S5
BPDPNDI reduction potential	E1Red = -850 mV vs Ag/AgCl	—	—	Figure Axis Exact Reported	S9 · Fig. S5 · Fig. S5

DFDNB solution · Model

1 mM DFDNB in 0.1 M Bu4NPF6/MeCN.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DFDNB reduction potential	E1Red = -810 mV vs Ag/AgCl	—	—	Figure Axis Exact Reported	S9 · Fig. S5 · Fig. S5

DNT solution · Model

1 mM DNT in 0.1 M Bu4NPF6/MeCN.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DNT reduction potential	E1Red = -850 mV vs Ag/AgCl	—	—	Figure Axis Exact Reported	S9 · Fig. S5 · Fig. S5

MV2+·2PF6- solution · Model

0.5 mM MV2+·2PF6- in 0.1 M Bu4NPF6/MeCN.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MV2+ reduction potential	E1Red = -380 mV vs Ag/AgCl	—	—	Figure Axis Exact Reported	S9 · Fig. S5 · Fig. S5

Pristine BMOF film on ZnO · Thin Film

BMOF films on ZnO-coated FTO electrodes; compared with BPDPNDI ligand

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BMOF oxidation potential	EOx = +920 mV vs Ag/AgCl	—	—	Text Exact Reported	896 · Results and discussion · Figure S5 referenced
BMOF reduction potential	ERed = -850 mV vs Ag/AgCl	—	—	Text Exact Reported	896 · Results and discussion · Figure S5 referenced
BMOF film absorption maximum	lambda max = 615 nm	—	—	Text Exact Reported	896 · Results and discussion · Figure S5 referenced
BPDPNDI ligand absorption maximum	lambda max = 610 nm	—	—	Text Exact Reported	896 · Results and discussion · Figure S5 referenced