Metal precursorsIron(II) acetate (86.97 mg, 0.5 mmol)
Linker precursorsquinizarin / 1,4-dihydroxyanthraquinone (120.1 mg, 0.5 mmol)
Solventswater (5 mL) plus ethanol (5 mL), 1:1 water-ethanol mixture
Atmospherenot reported for synthesis
Temperature175; then 90
Time72 h at 175 deg C; cooled to 90 deg C at 6 deg C/h; 48 h at 90 deg C; then cooled to room temperature
Substrate orientationnone; bulk autoclave synthesis
Oxidant / reductantnot reported
Work-upfiltered under vacuum; washed with hot ethanol and acetone; black precipitate obtained
ActivationFor the activated BET sample the paper states solvent exchange followed by heating in vacuo, but gives no activation solvent, temperature or time.
Scalability contextProduct obtained only in 1:1 water-ethanol; pure water or pure ethanol did not give FeQ. Authors note deposited layers on substrates remain a challenge.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|
| Metal Source | Iron(II) acetate | 86.97 mg, 0.5 mmol | p007 · 3. FeQ synthesis |
| Linker | quinizarin | 120.1 mg, 0.5 mmol | p007 · 3. FeQ synthesis |
| Solvent | water | 5 mL | p007 · 3. FeQ synthesis |
| Solvent | ethanol | 5 mL | p007 · 3. FeQ synthesis |