cMOF Evidence Base

Synthesis evidence

Unraveling the Electrical, Dielectric, and Electrocatalytic Properties of Bimetallic Cobalt-Based Metal–Organic Frameworks

Godara M., Chowdhury S., Cheng P. et al. · Advanced Energy and Sustainability Research · 2025 · 2300301

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Vague recipeSource: Main

Route 1: Unknown

main p.7 · Experimental Section

Metal precursorsCobalt(II) nitrate hexahydrate listed as chemical; exact Co-BTC recipe not specified in main text.
Linker precursorsNa-BTC linker/BTC implied but exact monometallic recipe not specified in main text.
SolventsWater/ethanol mixture is described for bimetallic route; monometallic solvent not separately specified.
Atmospherenot reported
Work-upnot reported for Co-BTC in main text
Activationnot reported
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcecobalt(II) nitrate hexahydrate (Co(NO3)2.6H2O, 99.5%)Not specifiedmain p.7 · Experimental Section
Linkerbenzene-1,3,5-tricarboxylic acid / Na-BTCNot specifiedmain p.7 · Experimental Section
Vague recipeSource: Main

Route 2: Unknown

main p.7 · Experimental Section

Metal precursorsManganese(II) nitrate tetrahydrate listed as chemical; exact Mn-BTC recipe not specified in main text.
Linker precursorsNa-BTC linker/BTC implied but exact monometallic recipe not specified in main text.
SolventsWater/ethanol mixture is described for bimetallic route; monometallic solvent not separately specified.
Atmospherenot reported
Work-upnot reported for Mn-BTC in main text
Activationnot reported
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcemanganese(II) nitrate tetrahydrate (Mn(NO3)2.4H2O, 99.5%)Not specifiedmain p.7 · Experimental Section
Linkerbenzene-1,3,5-tricarboxylic acid / Na-BTCNot specifiedmain p.7 · Experimental Section
Partial recipeSource: Main

Route 3: Other

main p.7 · Preparation of MOF Samples and Compaction into MOF Pellets

Metal precursorsMn(NO3)2.4H2O 90 mg (0.36 mmol); Co(NO3)2.6H2O 90 mg (0.31 mmol).
Linker precursorsNa-BTC linker, 80 mg, prepared by previous method.
SolventsWater/ethanol mixture (50:50 v/v): 10 mL for Mn precursor and 5 mL for Co precursor.
Atmospherenot reported
Temperatureroom temperature
Time2
Work-upCollected by centrifugation, washed sequentially with water/ethanol (50:50 v/v) and ethanol twice, then dried in a vacuum oven.
ActivationVacuum oven drying; temperature/time not reported.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceMn(NO3)2.4H2O90 mg (0.36 mmol)main p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
Metal SourceCo(NO3)2.6H2O90 mg (0.31 mmol)main p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
LinkerNa-BTC linker80 mgmain p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
Solventwater/ethanol mixture (50:50 v/v)10 mL for Mn solution; 5 mL for Co solutionmain p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
Partial recipeSource: Main

Route 4: Other

main p.7 · Preparation of MOF Samples and Compaction into MOF Pellets

Metal precursorsMn(NO3)2.4H2O 45 mg (0.18 mmol); Co(NO3)2.6H2O 90 mg (0.31 mmol).
Linker precursorsNa-BTC linker, 80 mg, prepared by previous method.
SolventsWater/ethanol mixture (50:50 v/v): 10 mL for Mn precursor and 5 mL for Co precursor.
Atmospherenot reported
Temperatureroom temperature
Time2
Work-upCollected by centrifugation, washed sequentially with water/ethanol (50:50 v/v) and ethanol twice, then dried in a vacuum oven.
ActivationVacuum oven drying; temperature/time not reported.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceMn(NO3)2.4H2O45 mg (0.18 mmol)main p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
Metal SourceCo(NO3)2.6H2O90 mg (0.31 mmol)main p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
LinkerNa-BTC linker80 mgmain p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
Solventwater/ethanol mixture (50:50 v/v)10 mL for Mn solution; 5 mL for Co solutionmain p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
Partial recipeSource: Main

Route 5: Other

main p.7 · Preparation of MOF Samples and Compaction into MOF Pellets

Metal precursorsMn(NO3)2.4H2O 180 mg (0.72 mmol); Co(NO3)2.6H2O 90 mg (0.31 mmol).
Linker precursorsNa-BTC linker, 80 mg, prepared by previous method.
SolventsWater/ethanol mixture (50:50 v/v): 10 mL for Mn precursor and 5 mL for Co precursor.
Atmospherenot reported
Temperatureroom temperature
Time2
Work-upCollected by centrifugation, washed sequentially with water/ethanol (50:50 v/v) and ethanol twice, then dried in a vacuum oven.
ActivationVacuum oven drying; temperature/time not reported.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceMn(NO3)2.4H2O180 mg (0.72 mmol)main p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
Metal SourceCo(NO3)2.6H2O90 mg (0.31 mmol)main p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
LinkerNa-BTC linker80 mgmain p.7 · Preparation of MOF Samples and Compaction into MOF Pellets
Solventwater/ethanol mixture (50:50 v/v)10 mL for Mn solution; 5 mL for Co solutionmain p.7 · Preparation of MOF Samples and Compaction into MOF Pellets