Measurement evidence
Synthesis, characterization, electrical conductivity, and catalytic studies of some coordination polymers of salen-type schiff base · Pardhi A.V., Bansod A.D., Yaul A.R. et al. · Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya · 2010 · 298-304
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
[Co(BNESAP)(H2O)2]n compressed pellet · Pellet
Styrene 5.2 g in 5 ml acetonitrile; catalyst 0.025 g; 40 C; 24 h; organic layer analysed by Shimadzu 14B GC with SE-30 column and FID.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| styrene conversion | 15-20 | — | — | Text Range | 302 · Results and discussion |
| styrene oxide selectivity | 49.70-67.51 | — | — | Text Range | 302 · Results and discussion |
[Fe(BNESAP)(H2O)2]n compressed pellet · Pellet
Styrene 5.2 g in 5 ml acetonitrile; catalyst 0.025 g; 40 C; 24 h; organic layer analysed by Shimadzu 14B GC with SE-30 column and FID.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| styrene conversion | 15-20 | — | — | Text Range | 302 · Results and discussion |
| styrene oxide selectivity | 49.70-67.51 | — | — | Text Range | 302 · Results and discussion |
[Mn(BNESAP)(H2O)2]n compressed pellet · Pellet
Styrene 5.2 g in 5 ml acetonitrile; catalyst 0.025 g; 40 C; 24 h; organic layer analysed by Shimadzu 14B GC with SE-30 column and FID.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| styrene conversion | 15-20 | — | — | Text Range | 302 · Results and discussion |
| styrene oxide selectivity | 49.70-67.51 | — | — | Text Range | 302 · Results and discussion |
[Ni(BNESAP)(H2O)2]n compressed pellet · Pellet
Styrene 5.2 g in 5 ml acetonitrile; catalyst 0.025 g; 40 C; 24 h; organic layer analysed by Shimadzu 14B GC with SE-30 column and FID.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| styrene conversion | 15-20 | — | — | Text Range | 302 · Results and discussion |
| styrene oxide selectivity | 49.70-67.51 | — | — | Text Range | 302 · Results and discussion |
[Cd(BNESAP)]n compressed pellet · Pellet
Elemental contents reported as found/calculated percentages; molecular weight estimated considering one unit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| colour | Mid buff | — | — | Table Qualitative | 300 · Table 1 · Table 1 |
| elemental analysis found/calculated | M 18.96/19.15; C 56.23/57.30; H 3.23/3.78; N 14.15/14.32 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
| molecular weight | 586.924 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
[Co(BNESAP)(H2O)2]n compressed pellet · Pellet
Elemental contents reported as found/calculated percentages; molecular weight estimated considering one unit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| colour | Light brown | — | — | Table Qualitative | 300 · Table 1 · Table 1 |
| elemental analysis found/calculated | M 10.20/10.35; C 59.82/59.05; H 4.42/4.60; N 14.52/14.76 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
| molecular weight | 569.477 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
[Cu(BNESAP)]n compressed pellet · Pellet
Elemental contents reported as found/calculated percentages; molecular weight estimated considering one unit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| colour | Orange buff | — | — | Table Qualitative | 300 · Table 1 · Table 1 |
| elemental analysis found/calculated | M 11.20/11.81; C 62.21/62.50; H 4.03/4.12; N 15.45/15.62 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
| molecular weight | 538.660 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
[Fe(BNESAP)(H2O)2]n compressed pellet · Pellet
Elemental contents reported as found/calculated percentages; molecular weight estimated considering one unit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| colour | Leaf brown | — | — | Table Qualitative | 300 · Table 1 · Table 1 |
| elemental analysis found/calculated | M 9.70/9.86; C 59.32/59.38; H 4.52/4.63; N 14.02/14.14 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
| molecular weight | 566.389 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
H2BNESAP compressed pellet · Pellet
Elemental contents reported as found/calculated percentages; molecular weight estimated considering one unit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| colour | Brown | — | — | Table Qualitative | 300 · Table 1 · Table 1 |
| elemental analysis found/calculated | C 70.20/70.57; H 4.82/5.08; N 17.35/17.64 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
| molecular weight | 476.569 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
[Mn(BNESAP)(H2O)2]n compressed pellet · Pellet
Elemental contents reported as found/calculated percentages; molecular weight estimated considering one unit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| colour | Dark brown | — | — | Table Qualitative | 300 · Table 1 · Table 1 |
| elemental analysis found/calculated | M 9.50/9.72; C 59.30/59.47; H 4.45/4.63; N 14.66/14.86 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
| molecular weight | 565.482 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
[Ni(BNESAP)(H2O)2]n compressed pellet · Pellet
Elemental contents reported as found/calculated percentages; molecular weight estimated considering one unit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| colour | Copper leaf | — | — | Table Qualitative | 300 · Table 1 · Table 1 |
| elemental analysis found/calculated | M 10.11/10.31; C 62.19/59.88; H 4.25/4.60; N 14.57/14.76 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
| molecular weight | 569.237 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
[Zn(BNESAP)]n compressed pellet · Pellet
Elemental contents reported as found/calculated percentages; molecular weight estimated considering one unit.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| colour | Leaf brown | — | — | Table Qualitative | 300 · Table 1 · Table 1 |
| elemental analysis found/calculated | M 12.15/12.11; C 62.05/62.29; H 4.02/4.11; N 15.40/15.57 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
| molecular weight | 539.904 | — | — | Table Exact Reported | 300 · Table 1 · Table 1 |
[Cd(BNESAP)]n compressed pellet · Pellet
TG analyses made from 40-700 C at heating rate 10 C min^-1 using gamma-Al2O3 reference on a PerkinElmer TGS-2 system.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Broido activation energy step 1 | 36.85 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 2 | 65.14 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 1 | 29.62 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 2 | 62.21 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| half decomposition temperature | 250 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
[Co(BNESAP)(H2O)2]n compressed pellet · Pellet
TG analyses made from 40-700 C at heating rate 10 C min^-1 using gamma-Al2O3 reference on a PerkinElmer TGS-2 system.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Broido activation energy step 1 | 37.16 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 2 | 27.54 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 3 | 85.01 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 1 | 38.23 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 2 | 29.23 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 3 | 80.23 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| half decomposition temperature | 330 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
[Cu(BNESAP)]n compressed pellet · Pellet
TG analyses made from 40-700 C at heating rate 10 C min^-1 using gamma-Al2O3 reference on a PerkinElmer TGS-2 system.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Broido activation energy step 1 | 35.12 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 2 | 65.15 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 1 | 31.25 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 2 | 60.23 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| half decomposition temperature | 421 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
[Fe(BNESAP)(H2O)2]n compressed pellet · Pellet
TG analyses made from 40-700 C at heating rate 10 C min^-1 using gamma-Al2O3 reference on a PerkinElmer TGS-2 system.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Broido activation energy step 1 | 40.12 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 2 | 23.12 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 3 | 72.13 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 1 | 39.35 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 2 | 17.29 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 3 | 89.92 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| half decomposition temperature | 250 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
H2BNESAP compressed pellet · Pellet
TG analyses made from 40-700 C at heating rate 10 C min^-1 using gamma-Al2O3 reference on a PerkinElmer TGS-2 system.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Broido activation energy step 1 | 32.51 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 1 | 30.82 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| half decomposition temperature | 140 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
[Mn(BNESAP)(H2O)2]n compressed pellet · Pellet
TG analyses made from 40-700 C at heating rate 10 C min^-1 using gamma-Al2O3 reference on a PerkinElmer TGS-2 system.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Broido activation energy step 1 | 39.33 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 2 | 21.12 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 3 | 84.89 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 1 | 32.82 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 2 | 25.75 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 3 | 86.90 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| half decomposition temperature | 230 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
[Ni(BNESAP)(H2O)2]n compressed pellet · Pellet
TG analyses made from 40-700 C at heating rate 10 C min^-1 using gamma-Al2O3 reference on a PerkinElmer TGS-2 system.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Broido activation energy step 1 | 45.10 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 2 | 29.36 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 3 | 89.81 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 1 | 42.65 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 2 | 31.25 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 3 | 74.47 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| half decomposition temperature | 350 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
[Zn(BNESAP)]n compressed pellet · Pellet
TG analyses made from 40-700 C at heating rate 10 C min^-1 using gamma-Al2O3 reference on a PerkinElmer TGS-2 system.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Broido activation energy step 1 | 33.15 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Broido activation energy step 2 | 67.15 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 1 | 30.32 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| Coats-Redfern activation energy step 2 | 62.36 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |
| half decomposition temperature | 370 | — | — | Table Exact Reported | 302 · Table 2 · Table 2 |