Spectroscopy — Synthesis, characterization, electrical conductivity, and catalytic studies of some coordination polymers of salen-type schiff base

7 measurement groups · 22 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

[Cd(BNESAP)]n compressed pellet · Pellet

Reflectance spectra recorded from 1350-350 nm on solid complexes diluted with MgO; magnetic susceptibility by Gouy method at room temperature.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electronic spectral bands	no d-d transitions	—	—	Text Qualitative	301 · Results and discussion
assigned coordination geometry	tetrahedral	—	—	Text Qualitative	301 · Results and discussion
magnetic behaviour	Diamagnetic	—	—	Table Qualitative	302 · Table 2 · Table 2

[Co(BNESAP)(H2O)2]n compressed pellet · Pellet

Reflectance spectra recorded from 1350-350 nm on solid complexes diluted with MgO; magnetic susceptibility by Gouy method at room temperature.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electronic spectral bands	9300; 16630	—	—	Text Exact Reported	301 · Results and discussion
assigned coordination geometry	octahedral	—	—	Text Qualitative	301 · Results and discussion
magnetic moment mu_eff	5.08	—	—	Table Exact Reported	302 · Table 2 · Table 2

[Cu(BNESAP)]n compressed pellet · Pellet

Reflectance spectra recorded from 1350-350 nm on solid complexes diluted with MgO; magnetic susceptibility by Gouy method at room temperature.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electronic spectral bands	17690; 19210; 24830	—	—	Text Exact Reported	301 · Results and discussion
assigned coordination geometry	square planar	—	—	Text Qualitative	301 · Results and discussion
magnetic moment mu_eff	1.87	—	—	Table Exact Reported	302 · Table 2 · Table 2

[Fe(BNESAP)(H2O)2]n compressed pellet · Pellet

Reflectance spectra recorded from 1350-350 nm on solid complexes diluted with MgO; magnetic susceptibility by Gouy method at room temperature.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electronic spectral bands	11300; 25000	—	—	Text Exact Reported	301 · Results and discussion
assigned coordination geometry	high spin octahedral	—	—	Text Qualitative	301 · Results and discussion
magnetic moment mu_eff	5.73	—	—	Table Exact Reported	302 · Table 2 · Table 2

[Mn(BNESAP)(H2O)2]n compressed pellet · Pellet

Reflectance spectra recorded from 1350-350 nm on solid complexes diluted with MgO; magnetic susceptibility by Gouy method at room temperature.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electronic spectral bands	14500; 19000; 25000	—	—	Text Exact Reported	301 · Results and discussion
assigned coordination geometry	octahedral	—	—	Text Qualitative	301 · Results and discussion
magnetic moment mu_eff	5.73	—	—	Table Exact Reported	302 · Table 2 · Table 2

[Ni(BNESAP)(H2O)2]n compressed pellet · Pellet

Reflectance spectra recorded from 1350-350 nm on solid complexes diluted with MgO; magnetic susceptibility by Gouy method at room temperature.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electronic spectral bands	10582; 17490; 24500	—	—	Text Exact Reported	301 · Results and discussion
assigned coordination geometry	octahedral	—	—	Text Qualitative	301 · Results and discussion
magnetic moment mu_eff	2.09	—	—	Table Exact Reported	302 · Table 2 · Table 2
magnetic moment mu_eff from discussion text	3.09	—	—	Text Exact Reported	301 · Results and discussion

[Zn(BNESAP)]n compressed pellet · Pellet

Reflectance spectra recorded from 1350-350 nm on solid complexes diluted with MgO; magnetic susceptibility by Gouy method at room temperature.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electronic spectral bands	no d-d transitions	—	—	Text Qualitative	301 · Results and discussion
assigned coordination geometry	tetrahedral	—	—	Text Qualitative	301 · Results and discussion
magnetic behaviour	Diamagnetic	—	—	Table Qualitative	302 · Table 2 · Table 2