Partial recipeSource: Main
Route 1: Other
2296 · Experimental Section - Synthesis of Ni(pc)Br
Metal precursors(Phthalocyaninato)nickel(II), Ni(pc), purchased from Eastman Kodak Co. and sublimed before use
Linker precursorsPreformed phthalocyaninato ligand in Ni(pc)
Solvents1,2,4-trichlorobenzene
AtmosphereSealed H-tube
Temperature150-160
Oxidant / reductantBr2(l) oxidant
Work-upCrystals formed in the cooler portion of the tube; no washing, isolation, or activation protocol reported.
Scalability contextSingle-crystal H-tube growth; products included needles, powder, microcrystalline material, and some unoxidised Ni(pc).
Show 3 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | (Phthalocyaninato)nickel(II) (Ni(pc)) | Not specified | 2296 · Experimental Section - Synthesis of Ni(pc)Br |
| Solvent | 1,2,4-trichlorobenzene | Not specified | 2296 · Experimental Section - Synthesis of Ni(pc)Br |
| Oxidant | Br2(l) | Not specified | 2296 · Experimental Section - Synthesis of Ni(pc)Br |