Complete recipeSource: Main
Route 1: Hydrothermal
main p.2 · 2.2. Synthesis of coordination polymers
Metal precursorsCuSO4.5H2O (0.2497 g, 1.00 mmol) and ZnSO4.H2O (0.1794 g, 1.00 mmol); Zn sulfate reported to influence decarboxylation but not coordinate in the product.
Linker precursors2,6-pydc acid (0.0836 g, 0.50 mmol) as in situ 2-pyc precursor; 1,10-phenanthroline monohydrate (0.0901 g, 0.50 mmol) present in one-pot mixture.
SolventsH2O (5.00 mL, 277.80 mmol).
AdditivesH3BO3 (0.0309 g, 0.50 mmol); ZnSO4.H2O acts as a sulfate salt additive/catalyst for decarboxylation.
AtmosphereAutogenous pressure in a 23 mL PTFE-lined stainless steel/Parr acid reactor.
Temperature180
Time120
Work-upStirred 30 min at room temperature before heating; cooled to room temperature; mixed crystals washed with pure water and dried at room temperature.
ActivationNo activation reported.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | CuSO4.5H2O | 0.2497 g, 1.00 mmol | main p.2 · 2.2. Synthesis of coordination polymers |
| Additive | ZnSO4.H2O | 0.1794 g, 1.00 mmol | main p.2 · 2.2. Synthesis of coordination polymers |
| Linker | 2,6-pydc acid | 0.0836 g, 0.50 mmol | main p.2 · 2.2. Synthesis of coordination polymers |
| Linker | 1,10-phenanthroline monohydrate | 0.0901 g, 0.50 mmol | main p.2 · 2.2. Synthesis of coordination polymers |
| Additive | H3BO3 | 0.0309 g, 0.50 mmol | main p.2 · 2.2. Synthesis of coordination polymers |
| Solvent | H2O | 5.00 mL, 277.80 mmol | main p.2 · 2.2. Synthesis of coordination polymers |