Metal precursorsZn(NO3)2.6H2O (reported as Zn(NO)3.6H2O in text), 0.06 g, 0.2 mmol, in H2O
Linker precursors4-nvp (0.046 g, 0.2 mmol) in MeOH; H2fum (0.023 g, 0.2 mmol) neutralised with Et3N in EtOH
SolventsMeOH 2 mL; H2O 2 mL; 2 mL 1:1 MeOH/H2O buffer layer; EtOH 2 mL
AdditivesEt3N (0.021 g, 0.2 mmol) for neutralisation of H2fum
Atmospherenot specified; ambient layering inferred
Temperatureroom temperature/not specified
Time72
Work-upyellow needle-shaped crystals collected after three days; isolation/washing not specified
Activationnone reported for as-synthesised crystals
Scalability contextLayered crystallisation produced 0.095 g, 70% yield; no scale-up data.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|
| Linker | 4-nvp | 0.046 g, 0.2 mmol · in MeOH (2 mL) | 2 · Synthesis of compound 1 |
| Metal Source | Zn(NO)3.6H2O / Zn(NO3)2.6H2O | 0.06 g, 0.2 mmol · in H2O (2 mL) | 2 · Synthesis of compound 1 |
| Solvent | MeOH/H2O buffer | 2 mL · 1:1 v/v | 2 · Synthesis of compound 1 |
| Linker | H2fum | 0.023 g, 0.2 mmol · in EtOH (2 mL) | 2 · Synthesis of compound 1 |
| Base | Et3N | 0.021 g, 0.2 mmol · neutralised H2fum | 2 · Synthesis of compound 1 |
| Solvent | EtOH | 2 mL | 2 · Synthesis of compound 1 |