Zhang B., Dong G., Wang L. et al. · Catalysis Science and Technology · 2017 · 4971-4976
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
FMBV-2, the middle MIL-53(Fe) loading, is the optimum MIL-53(Fe)-modified 2% Mo:BiVO4 photoanode in the tested series.
Caveat: Some loading-series values are figure-read estimates; the optimum conclusion is directly stated by the authors.
4 · Results and discussion · Fig. S8; Fig. S9 · Linked to 4 structured results
FMBV-2 enables stable PEC water splitting with approximately stoichiometric H2/O2 evolution over 2 h.
Caveat: H2/O2 amounts at 120 min are visually estimated from the SI plot; the 2:1 stoichiometric ratio is text-stated.
5 · Results and discussion · Fig. S11 · Linked to 4 structured results
MIL-53(Fe) serves as an efficient hole-transfer co-catalyst that improves the PEC performance of Mo-doped BiVO4 photoanodes for water oxidation.
Caveat: The paper supports this by PEC/EIS application metrics but does not directly measure intrinsic MIL-53(Fe) conductivity.
1 · Abstract · Linked to 4 structured results
The synthesised MIL-53(Fe) is assigned to the crystalline monoclinic MIL-53(Fe) framework, while the FMBV composite retains monoclinic BiVO4 diffraction features.
Caveat: MIL-53(Fe) peaks are not visible in FMBV XRD; composite assignment additionally relies on microscopy, XPS and FTIR.
3-4 · Results and discussion · Fig. 1; Fig. 3; Fig. S4 · Linked to 3 structured results
The MIL-53(Fe)/2% Mo:BiVO4 junction facilitates hole transfer to the electrolyte and suppresses electron-hole recombination.
Caveat: Mechanistic assignment is inferred from PEC, EIS and schematic band/charge-transport arguments rather than direct transient spectroscopy or conductivity data.
5 · Results and discussion · Scheme 2 · Linked to 3 structured results
Mo doping improves BiVO4 PEC efficiency by increasing charge-carrier concentration without changing the indirect band-gap nature.
Caveat: The specific statement about indirect band gap and Mott-Schottky confirmation is attributed to prior studies cited by the paper, not newly measured here.
5 · Results and discussion · Scheme 2 · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Nanoporous BiVO4 photoanode | BiVO4Bi and V oxide semiconductor lattice | 3D · PristineMonoclinic bismuth vanadate, JCPDS No. 14-0688. | 4 · Results and discussion · Fig. 3A |
| BiVO4-MIL-53(Fe) composite photoanode | MIL-53(Fe) on BiVO4Fe(III) MIL-53 chains plus Bi/V oxide semiconductor · Terephthalate in MIL-53(Fe) | 3D · CompositeMIL-53(Fe)-modified BiVO4 composite films used as non-Mo-doped application controls. | 6 · Supplemental Figures · Fig. S8 |
| 2% Mo:BiVO4-MIL-53(Fe) composite photoanode (FMBV) | MIL-53(Fe) on 2% Mo:BiVO4Fe(III) MIL-53 chains plus Bi/V/Mo oxide semiconductor · Terephthalate in MIL-53(Fe) | 3D · CompositeComposite of MIL-53(Fe) hexagonal bipyramids deposited on nanoporous 2% Mo:BiVO4; BiVO4 phase remains monoclinic. | 3 · Results and discussion · Scheme 1; Fig. 2 |
| MIL-53(Fe) | Fe(OH){O2C-C6H4-CO2}Fe(III) octahedral chains sharing OH groups · Terephthalate / benzene-1,4-dicarboxylate | 3D · PristineMIL-53(Fe) framework; monoclinic symmetry by XRD; 3D framework with a one-dimensional pore channel system. | 1, 3 · Introduction; Results and discussion · Fig. 1 |
| 2% Mo:BiVO4 photoanode | Mo-doped BiVO4; Bi:V:Mo = 0.98:1:0.02Bi, V and Mo oxide semiconductor lattice | 3D · PristineMo-doped monoclinic bismuth vanadate photoanode. | 2 · Preparation of nanoporous BiVO4 and 2% Mo:BiVO4 photoanodes |
| 2% Mo:BiVO4/FeOOH composite photoanode | FeOOH on 2% Mo:BiVO4Fe oxyhydroxide on Bi/V/Mo oxide semiconductor | unknown · CompositeFeOOH co-catalyst-modified 2% Mo:BiVO4 control. | 2 · Preparation of 2%Mo:BiVO4-FeOOH composite materials |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| nanoporous BiVO4 photoanoderesearch_0461__mat__mat_bivo4 | Electrode · Pristine Control · Unknown | Drop-cast precursor on FTO; dried at 150 deg C for 60 min; annealed in air at 500 deg C for 2.5 h.FTO glass, 1 x 5 cm2 | 2 · Preparation of nanoporous BiVO4 and 2% Mo:BiVO4 photoanodes |
| BVO/MIL-53(Fe)-1research_0461__mat__mat_bvo_mil53 | Electrode · Composite Sample · Composite | MIL-53(Fe)-modified BiVO4 film; exact loading inferred as the lower-loading comparison series but not explicitly assigned in text.FTO glass | 6 · Supplemental Figures · Fig. S8 |
| BVO/MIL-53(Fe)-2research_0461__mat__mat_bvo_mil53 | Electrode · Composite Sample · Composite | MIL-53(Fe)-modified BiVO4 film; exact loading inferred as the middle-loading comparison series but not explicitly assigned in text.FTO glass | 6 · Supplemental Figures · Fig. S8 |
| BVO/MIL-53(Fe)-3research_0461__mat__mat_bvo_mil53 | Electrode · Composite Sample · Composite | MIL-53(Fe)-modified BiVO4 film; exact loading inferred as the higher-loading comparison series but not explicitly assigned in text.FTO glass | 6 · Supplemental Figures · Fig. S8 |
| FMBV-1research_0461__mat__mat_fmbv | Electrode · Composite Sample · Composite | MIL-53(Fe) spin-coated onto 2% Mo:BiVO4 using 350 uL coating amount, then dried at 150 deg C for 1 h.FTO glass | 3 · Results and discussion · Scheme 1 |
| FMBV-2 / 2% Mo:BiVO4-MIL-53(Fe)research_0461__mat__mat_fmbv | Electrode · Target Sample · Composite | MIL-53(Fe) spin-coated onto 2% Mo:BiVO4 using 450 uL coating amount, then dried at 150 deg C for 1 h.FTO glass | 3-5 · Results and discussion · Fig. 2; Fig. 4; Fig. S9 |
| FMBV-3research_0461__mat__mat_fmbv | Electrode · Composite Sample · Composite | MIL-53(Fe) spin-coated onto 2% Mo:BiVO4 using 550 uL coating amount, then dried at 150 deg C for 1 h.FTO glass | 3 · Results and discussion · Scheme 1 |
| pure MIL-53(Fe) photoanoderesearch_0461__mat__mat_mil53_fe | Electrode · Pristine Control · Pristine Framework | Pure MIL-53(Fe) electrode used for current-potential measurement.not specified | 5 · Supplemental Figures · Fig. S6 |
| as-prepared MIL-53(Fe) powderresearch_0461__mat__mat_mil53_fe | Powder · Composite Component · Pristine Framework | Microwave-synthesised powder, centrifuged, washed and vacuum-dried. | 2 · Preparation of MIL-53(Fe) |
| 2% Mo:BiVO4 photoanoderesearch_0461__mat__mat_mo_bivo4 | Electrode · Pristine Control · Doped | Prepared by the BiVO4 drop-cast/anneal route with ammonium molybdate added at Bi:V:Mo = 0.98:1:0.02.FTO glass, 1 x 5 cm2 | 2 · Preparation of nanoporous BiVO4 and 2% Mo:BiVO4 photoanodes |
| 2% Mo:BiVO4/FeOOH-1research_0461__mat__mat_mo_bivo4_feooh | Electrode · Composite Sample · Composite | FeOOH photoelectron-deposited on 2% Mo:BiVO4 for 10 min.FTO glass | 2 · Preparation of 2%Mo:BiVO4-FeOOH composite materials |
| 2% Mo:BiVO4/FeOOH-2research_0461__mat__mat_mo_bivo4_feooh | Electrode · Composite Sample · Composite | FeOOH photoelectron-deposited on 2% Mo:BiVO4 for 20 min.FTO glass | 4-5 · Results and discussion · Fig. 4; Fig. S10 |
| 2% Mo:BiVO4/FeOOH-3research_0461__mat__mat_mo_bivo4_feooh | Electrode · Composite Sample · Composite | FeOOH photoelectron-deposited on 2% Mo:BiVO4 for 30 min.FTO glass | 2 · Preparation of 2%Mo:BiVO4-FeOOH composite materials |