Paul S., Dutta B., Das P. et al. · Applied Organometallic Chemistry · 2023 · e7160
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Zn(II)-CP shows strongest cytotoxic activity against HeLa cells and induces ROS-associated apoptosis, G2/M arrest and caspase activation.
Caveat: Biological data are application context rather than conductive-MOF transport evidence.
10 · 4 Conclusion · Linked to 5 structured results
The low optical band gap and measurable conductivity motivated fabrication of a Zn(II)-CP Schottky diode.
Caveat: Transport is reported for a spin-coated thin film with incomplete DMF solution concentration/loading details.
10 · 4 Conclusion · Linked to 4 structured results
The DFT HOMO-LUMO gap differs from the experimental band gap, which the authors attribute to modelling only a single monomeric unit rather than the extended CP.
4 · 3.2 Opto-electrical property · Figure 3 · Linked to 4 structured results
Zn(II)-CP is assigned as a pristine 2D square-grid Zn(II) coordination polymer with BDC bridges and terminal QPR ligands.
Caveat: PXRD phase-purity evidence is qualitative; full CIF coordinates were not part of the assigned local documents.
4 · 3.1 Crystal structure · Figure 1 · Linked to 8 structured results
The authors attribute conductivity to metal-dependent charge transport through non-covalent bonding interactions rather than through-bond transport through Zn-O carboxylate or organic-ligand backbones.
Caveat: Mechanistic interpretation is qualitative and supported by DFT discussion rather than direct charge-transport pathway measurement.
4 · 3.2 Opto-electrical property · Linked to 2 structured results
Light irradiation improves the Zn(II)-CP thin-film conductivity by about 15% and yields a near-ideal diode ideality factor of 0.99.
Caveat: No raw I-V data are provided in the supplied text; extraction relies on Table 1.
4 · 3.2 Opto-electrical property · Table 1 · Linked to 4 structured results
Forward-bias transport is interpreted as Ohmic in region I and trap-assisted space-charge-limited conduction in region II.
Caveat: Region slopes are described approximately in the main text and not digitised from the plotted data.
5-6 · 3.2 Opto-electrical property · Figure 5 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| 7-[(pyridin-4-ylmethylene)-amino]-chromen-2-one (QPR) | C15H10N2O2none · coumarinyl-pyridyl Schiff base | 0D · Pristinemolecular ligand precursor | 2 · 2.1.1 Synthetic procedure of 7-[(pyridin-4-ylmethylene)-amino]-chromen-2-one (QPR) · Scheme 1 |
| [Zn2(BDC)4(QPR)2(H2O)]n (Zn(II)-CP) | [Zn2(BDC)4(QPR)2(H2O)]n; elemental-analysis formula reported as C24H18N2O7ZnZn(II) paddle-wheel units; distorted square-pyramidal ZnO4N coordination · BDC2- = 1,4-benzenedicarboxylato; QPR = 7-[(pyridin-4-ylmethylene)-amino]-chromen-2-one | 2D · Pristinetriclinic P-1, Z = 2; 2D square-grid coordination polymer with 3D supramolecular assembly | 1 · Abstract |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| QPR light-brown crystalline ligandresearch_0471__mat__qpr_ligand | Single Crystal · Target Sample · Unknown | filtered and slow-evaporated after Schiff-base reaction | 2 · 2.1.1 · Scheme 1 |
| as-synthesised powdered Zn(II)-CPresearch_0471__mat__zncp | Powder · Target Sample · Pristine Framework | as-synthesised bulk material | 4 · 3.1 Crystal structure · Figure S7 |
| DFT model of Zn(II)-CP asymmetric unitresearch_0471__mat__zncp | Model · Model System · Model | gas-phase geometry optimisation using SCXRD coordinates | DFT computation |
| ITO/Zn(II)-CP/Al Schottky diode thin filmresearch_0471__mat__zncp | Thin Film · Target Sample · Pristine Framework | spin-coated from DMF solution on ITO, vacuum dried, Al evaporatedITO-coated glass with evaporated Al top electrode · nearly one micrometer | Fabrication and characterization of ITO/Compound/Al based Schottky Barrier Diode |
| Zn(II)-CP single crystalresearch_0471__mat__zncp | Single Crystal · Target Sample · Pristine Framework | brown block crystal from slow liquid-layer diffusion | 3 · X-Ray Diffraction Measurement · Table S1 |